A non-innocent, π-extended N-heterobicyclic carbene–thiolate ligand
A bidentate NHC-thiolate ligand based on the imidazo[1,5-<i>a</i>]pyridine scaffold and featuring an extended π-system is described. It is derived from a readily available zwitterionic precursor and the chemistry of the corresponding homoleptic Ni(II) complex is investigated.
Authors
- Stéphanie Bastin (ORCID: https://orcid.org/0000-0002-7512-7423)
- Michael Marquardt
- Alix Sournia‐Saquet (ORCID: https://orcid.org/0000-0001-7811-6984)
- Laure Vendier (ORCID: https://orcid.org/0000-0002-7111-9258)
- Vincent Maurel (ORCID: https://orcid.org/0000-0002-0855-6412)
- Iván Castillo (ORCID: https://orcid.org/0000-0002-4876-4339)
- Vincent César (ORCID: https://orcid.org/0000-0002-6203-6434)
- Jean‐Marie Mouesca (ORCID: https://orcid.org/0000-0001-7497-1430)
Institutions
- Centre National de la Recherche Scientifique (FR)
- Université Toulouse III - Paul Sabatier (FR)
- Université Fédérale de Toulouse Midi-Pyrénées (FR)
- Commissariat à l'Énergie Atomique et aux Énergies Alternatives (FR)
- CEA Grenoble (FR)
- Laboratoire de Chimie de Coordination (FR)
- Universidad Nacional Autónoma de México (MX)
- Université Grenoble Alpes (FR)
Publication Details
- Journal
- Chemical Communications
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5cc02841h
- Primary Topic
- N-Heterocyclic Carbenes in Organic and Inorganic Chemistry
- Type
- article
- Field-Weighted Citation Impact
- 0.00
Funders
- Centre National de la Recherche Scientifique
- Dirección General de Asuntos del Personal Académico, Universidad Nacional Autónoma de México