Dual photoredox/palladium-catalyzed three-component reaction for the synthesis of trifluoromethylated allylic alcohols

An effective three-component reaction using simple and easily obtained cyclic vinyl carbonates, olefins and CF<sub>3</sub>SO<sub>2</sub>Na under dual photoredox/palladium catalysis was documented for the synthesis of trifluoromethylated allylic alcohols bearing quaternary carbon centers with high stereoselectivity.

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Publication Details

Journal
Organic & Biomolecular Chemistry
Published
2025-01-01
DOI
https://doi.org/10.1039/d5ob00926j
Primary Topic
Fluorine in Organic Chemistry
Type
article
Field-Weighted Citation Impact
0.00

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article

Dual photoredox/palladium-catalyzed three-component reaction for the synthesis of trifluoromethylated allylic alcohols

Xiaoming Zhao, Kavuri Rupa, Sheng‐Cai Zheng, Xiaolin Wang
Organic & Biomolecular Chemistry
Fluorine in Organic Chemistry
article

Dual photoredox/palladium-catalyzed three-component reaction for the synthesis of trifluoromethylated allylic alcohols

Xiaoming Zhao, Kavuri Rupa, Sheng‐Cai Zheng, Xiaolin Wang
article en

Abstract

An effective three-component reaction using simple and easily obtained cyclic vinyl carbonates, olefins and CF<sub>3</sub>SO<sub>2</sub>Na under dual photoredox/palladium catalysis was documented for the synthesis of trifluoromethylated allylic alcohols bearing quaternary carbon centers with high stereoselectivity.

Organic & Biomolecular ChemistryVol. 23(28)
Tongji University (CN)
National Natural Science Foundation of China, Tongji University, Fundamental Research Funds for the Central Universities
Clean water and sanitation
Openalex Percentile: Top 89%
Fluorine in Organic Chemistry
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