Impact of Bi and its oxide phases on Bi<sub>2</sub>S<sub>3</sub> compound transformation and photoelectrochemical performance

Bi<sub>2</sub>S<sub>3</sub> films were synthesized by sulfurizing sputtered Bi and Bi<sub>2</sub>O<sub>3</sub> (α, β phases). Metallic Bi enabled a more efficient conversion, while Bi<sub>2</sub>O<sub>3</sub> impeded Bi<sub>2</sub>S<sub>3</sub> formation due to its strong Bi-O bonds. Sulfur distribution along film depth significantly affected photoelectrochemical (PEC) performance, underscoring the critical importance of precursor selection for optimized functionality.

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Journal
Chemical Communications
Published
2025-01-01
DOI
https://doi.org/10.1039/d5cc02420j
Primary Topic
Gas Sensing Nanomaterials and Sensors
Type
article
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Impact of Bi and its oxide phases on Bi2S3 compound transformation and photoelectrochemical performance

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article en

Abstract

Bi<sub>2</sub>S<sub>3</sub> films were synthesized by sulfurizing sputtered Bi and Bi<sub>2</sub>O<sub>3</sub> (α, β phases). Metallic Bi enabled a more efficient conversion, while Bi<sub>2</sub>O<sub>3</sub> impeded Bi<sub>2</sub>S<sub>3</sub> formation due to its strong Bi-O bonds. Sulfur distribution along film depth significantly affected photoelectrochemical (PEC) performance, underscoring the critical importance of precursor selection for optimized functionality.

Chemical CommunicationsVol. 61(62)
Universidade Federal do Rio Grande do Sul (BR)
Affordable and clean energy
Openalex Percentile: Top 88%
Gas Sensing Nanomaterials and Sensors
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Impact of Bi and its oxide phases on Bi<sub>2</sub>S<sub>3</sub> compound transformation and photoelectrochemical performance — Anderson Thesing, Sherdil Khan, et al. · Chemical Communications (2025) | TGRS Research Map | TGRS