Synthesis and Electrochemical Properties of Derivatives from Fe‐Based Metal‐Organic Frameworks

Metal‐organic frameworks (MOFs) demonstrate promising potential as electrode materials in supercapacitors. Herein, a straightforward approach for synthesizing the Fe‐based MOF (FeMOF) via a hydrothermal method is reported. FeMOF‐derived materials are obtained after the following calcination, and they convert to Fe 2 O 3 at temperatures higher than 400 °C. The FeMOF derivative calcined at 500 °C demonstrates a significant specific capacitance of 133.39 F g −1 at a current density of 1 A g −1 . The FeMOF‐500 material exhibits excellent cycling stability, retaining 74% of its capacitance after 5000 cycles at 15 A g −1 . The results of electrochemical impedance spectroscopy reveal low internal resistance and charge transfer resistance, demonstrating their superior electrical conductivity and charge storage capacity. This study not only presents a novel strategy for developing high‐performance MOF‐based supercapacitor electrode materials but also holds significant promise for advancing sustainable energy storage technologies.

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Publication Details

Journal
physica status solidi (RRL) - Rapid Research Letters
Published
2025-06-20
DOI
https://doi.org/10.1002/pssr.202500122
Citations
2
Primary Topic
Supercapacitor Materials and Fabrication
Type
article
Field-Weighted Citation Impact
0.85

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article

Synthesis and Electrochemical Properties of Derivatives from Fe‐Based Metal‐Organic Frameworks

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2 citations
physica status solidi (RRL) - Rapid Research Letters
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article

Synthesis and Electrochemical Properties of Derivatives from Fe‐Based Metal‐Organic Frameworks

Yiliang Lv, Jingyu Shi, Hao Yu, X. W. Wang, Bihui Zhang, Cong Liu, Yifan Wang, Yi Chen, Rui Liu, Yan Zhang, Ruixue Sun, Z. Z. Xing, E. Fan, Peiao Lu
article en
2 citations

Abstract

Metal‐organic frameworks (MOFs) demonstrate promising potential as electrode materials in supercapacitors. Herein, a straightforward approach for synthesizing the Fe‐based MOF (FeMOF) via a hydrothermal method is reported. FeMOF‐derived materials are obtained after the following calcination, and they convert to Fe 2 O 3 at temperatures higher than 400 °C. The FeMOF derivative calcined at 500 °C demonstrates a significant specific capacitance of 133.39 F g −1 at a current density of 1 A g −1 . The FeMOF‐500 material exhibits excellent cycling stability, retaining 74% of its capacitance after 5000 cycles at 15 A g −1 . The results of electrochemical impedance spectroscopy reveal low internal resistance and charge transfer resistance, demonstrating their superior electrical conductivity and charge storage capacity. This study not only presents a novel strategy for developing high‐performance MOF‐based supercapacitor electrode materials but also holds significant promise for advancing sustainable energy storage technologies.

physica status solidi (RRL) - Rapid Research LettersVol. 19(9)
Nanyang Normal University (CN), Anyang Normal University (CN), Chongqing University of Technology (CN), Henan Normal University (CN)
Chongqing University, Chongqing University of Technology, Nanyang Normal University, Centre Scientifique et Technique du Bâtiment
Openalex Percentile: Top 27%
Supercapacitor Materials and Fabrication
0.85
DOIOpen Access PDFOpenAlex
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