Femtosecond Laser-Modulated Oxygen Vacancies in LiFePO4 Thick Electrodes for Rapid Ion Transport

Although thick electrodes hold significant potential for enhancing battery energy density, their practical application is limited by restricted ion transport kinetics. Constructing porous structures within thick electrodes is a widely adopted strategy to address this limitation, but it often compromises mass retention and mechanical integrity. In this study, a microchannel structure that balances the electrochemical and mechanical properties of the electrode was identified through simulation and precisely fabricated using femtosecond laser technology. Furthermore, the ultra-short pulse duration and high pulse energy of femtosecond lasers introduce oxygen vacancies into the electrode material, thereby enhancing its electrical conductivity. The obtained electrode exhibited excellent electrochemical performance under high-rate charging and discharging conditions, achieving significantly enhanced cycling stability and capacity retention, with a capacity 1.99 times greater than that of the unstructured electrode after 100 cycles. Meanwhile, the mechanical stability of the laser-processed electrode was maintained. This study provides new insights into the structural design and processing of the thick electrode and contributes to advancements in the field of energy storage.