The superiority of W <sup>6+</sup> overturns the CO <sub>2</sub> hydrogenation selectivity of iridium

Incorporating the W<sup>6+</sup> state into nanostructured ceria effectively shifts the overwhelming CH<sub>4</sub> selectivity on fresh Ir nanocluster surfaces towards CO, achieving over 99.0% selectivity while maintaining outstanding activity and long-term catalytic stability.

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Publication Details

Journal
Chemical Communications
Published
2025-01-01
DOI
https://doi.org/10.1039/d5cc02796a
Citations
1
Primary Topic
Ammonia Synthesis and Nitrogen Reduction
Type
article
Field-Weighted Citation Impact
0.39

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article

The superiority of W 6+ overturns the CO 2 hydrogenation selectivity of iridium

Yixin Lian, Zhaojun Wen, Haiqiang Lin, Xinping Duan et al.
1 citations
Chemical Communications
Ammonia Synthesis and Nitrogen Reduction
0.39
article

The superiority of W 6+ overturns the CO 2 hydrogenation selectivity of iridium

Yixin Lian, Zhaojun Wen, Haiqiang Lin, Xinping Duan, Weizhou Jiao, Ruixin Wang, Xuelian Liang
article en
1 citations

Abstract

Incorporating the W<sup>6+</sup> state into nanostructured ceria effectively shifts the overwhelming CH<sub>4</sub> selectivity on fresh Ir nanocluster surfaces towards CO, achieving over 99.0% selectivity while maintaining outstanding activity and long-term catalytic stability.

Chemical CommunicationsVol. 61(62)
North University of China (CN), Xiamen University (CN), Collaborative Innovation Center of Chemistry for Energy Materials (CN)
National Natural Science Foundation of China, Shanxi Provincial Education Department
Openalex Percentile: Top 43%
Ammonia Synthesis and Nitrogen Reduction
0.39
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