Nickel-Catalyzed Hydrocarboxylation of Styrenes with Carbon Dioxide and Water

The nickel-catalyzed hydrocarboxylation of styrenes with carbon dioxide, employing water as a formal hydride source, has been effectively established, yielding the α-aryl carboxylic acid with commendable regioselectivity and yield. Furthermore, the catalytic asymmetric hydrocarboxylation of styrenes has been established, albeit with limited enantioselectivity.

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Publication Details

Journal
The Journal of Organic Chemistry
Published
2025-06-18
DOI
https://doi.org/10.1021/acs.joc.5c00325
Citations
2
Primary Topic
Carbon dioxide utilization in catalysis
Type
article
Field-Weighted Citation Impact
1.41

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article

Nickel-Catalyzed Hydrocarboxylation of Styrenes with Carbon Dioxide and Water

Y.Y. Chen, Haoyu Zhang, Ruoxi Yu, Lingyun Huang
2 citations
The Journal of Organic Chemistry
Carbon dioxide utilization in catalysis
1.41
article

Nickel-Catalyzed Hydrocarboxylation of Styrenes with Carbon Dioxide and Water

Y.Y. Chen, Haoyu Zhang, Ruoxi Yu, Lingyun Huang
article en
2 citations

Abstract

The nickel-catalyzed hydrocarboxylation of styrenes with carbon dioxide, employing water as a formal hydride source, has been effectively established, yielding the α-aryl carboxylic acid with commendable regioselectivity and yield. Furthermore, the catalytic asymmetric hydrocarboxylation of styrenes has been established, albeit with limited enantioselectivity.

The Journal of Organic ChemistryVol. 90(26)
Zhejiang Sci-Tech University (CN)
China Postdoctoral Science Foundation, Zhejiang Sci-Tech University, Natural Science Foundation of Zhejiang Province
Clean water and sanitation
Openalex Percentile: Top 23%
Carbon dioxide utilization in catalysis
1.41
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