CB<sub>5</sub>Pd<sub>5</sub><sup>+</sup>: a boron-based global minimum with a planar pentacoordinate carbon
The designed boron-based planar pentacoordinate carbon (ppC) cluster CB 5 Pd 5 ⁺ is 45.1 kcal mol −1 lower in energy than its planar pentacoordinate boron isomer, demonstrating that transition metals stabilize ppC clusters as effectively as chalcogens.
Authors
- Yan‐Bo Wu (ORCID: https://orcid.org/0000-0001-6032-9957)
- Bo Jin (ORCID: https://orcid.org/0000-0002-6401-9961)
- Xiao‐Ling Guan (ORCID: https://orcid.org/0009-0005-8235-5212)
- Caixia Yuan (ORCID: https://orcid.org/0000-0002-3681-4423)
- X. Wu
- Rui Sun (ORCID: https://orcid.org/0009-0000-2849-0767)
Institutions
- Shanxi Agricultural University (CN)
- Shanxi University (CN)
- Xinzhou Teachers University (CN)
Publication Details
- Journal
- New Journal of Chemistry
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5nj01539a
- Citations
- 2
- Primary Topic
- Synthesis and Properties of Aromatic Compounds
- Type
- article
- Field-Weighted Citation Impact
- 1.87
Funders
- Natural Science Foundation of Shanxi Province
- Shanxi Provincial Education Department
- Shanxi Agricultural University