Utilizing enantiomerically pure organic spacers for anion-centred clusters in a hybrid inorganic–organic lead-halide crystal
In this work, we present structural data of the novel, chiral material (<i>S</i>-2AH)<sub>4</sub>[Pb<sub>2</sub>Br<sub>7</sub>]Br obtained from single crystal X-ray diffraction (SCXRD). This quasi-2D material displays anion-centred clusters within its organic layer, without the need for bi-functional spacers. Instead, the structure is based on the steric properties of the used enantiomerically pure precursors.
Authors
- Markus W. Heindl (ORCID: https://orcid.org/0000-0001-7968-617X)
- Joachim Ballmann (ORCID: https://orcid.org/0000-0001-6431-4197)
- Felix Deschler (ORCID: https://orcid.org/0000-0002-0771-3324)
Institutions
- Heidelberg University (DE)
Publication Details
- Journal
- Chemical Communications
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5cc01101a
- Primary Topic
- Perovskite Materials and Applications
- Type
- article
- Field-Weighted Citation Impact
- 0.00
Funders
- European Research Council