The Plasticization of Alkali-Activated Cement System Na2O-CaO-Al2O3-SiO2-H2O: Problems and Decisions

The paper is devoted to the plasticization mechanisms of alkali-activated cement system Na2O-CaO-Al2O3-SiO2-H2O. The fundamentals and basic factors determining the effectiveness of plasticizing surfactants for alkali-activated cement materials are discussed. The factors under consideration in the study were alkali-activated cement basicity (the content of granulated blast furnace slag), the anion of the alkaline component or activator, and the degree of dispersing of the cement particles in the system. The action effect of plasticizers was determined by finding the interrelation between the stability of its molecular structure, degree of adsorption, and molecular weight depending on mentioned basic factors. A systematic approach to the systematization of surfactants and their choice to be taken into consideration to control technology-related and physico-mechanical properties of alkali-activated cement-based heavyweight concretes, building mortars, and lightened grouts has been proposed.