Modification of Chabazite Using Hexadecyltrime-Thylammonium Bromide (HDTMA-Br) for Chromium(VI) Removal from Water Solutions

Chabazite, a tectosilicate mineral, belongs to the zeolite group and has been widely used for the adsorptive removal of a number of cationic contaminants from the aqueous phase. However, a negatively charged chabazite surface can be altered by chemical modification in order to change its adsorption abilities towards anions. This study reports the potential for the removal of hexavalent chromium ions from aqueous solutions by modified chabazite. In this regard, natural chabazite was modified by the immobilization of HDTMA-Br to achieve double-layer coverage on its surface, defined as the double external cation exchange capacity. Next, a batch adsorption system was applied to study the adsorption of inorganic Cr(VI) anions from aqueous solutions. The process equilibrium was described by 11 theoretical isotherm equations, while 6 adsorption kinetics were represented by four models. Among those tested, the most appropriate model for the description of the studied process kinetics was the pseudo-second order irreversible model. The obtained results suggest that Cr(VI) adsorption takes place according to a complex mechanism comprising both Langmuir-type sorption with the maximum adsorption capacity of modified chabazite, approx. 9.3-9.9 mg g^-1, and the trapping of Cr(VI) inside the capillaries of the amorphous sorbent, making it a viable option for water treatment applications.