Selective hydrosilylation of olefins by a two-dimensional Rh(<scp>i</scp>) low-valent metal–organic framework

Multitopic phosphine ligands combined with Rh(I) or Ir(I) nodes are shown to assemble into low-valent metal-organic frameworks (LVMOFs) with a two-dimensional (2D) topology. The 2D Rh(I) LVMOF exhibits catalytic activity for the hydrosilylation of olefins, functioning in a heterogeneous and selective manner.

Authors

Marilena Esposito (ORCID: https://orcid.org/0000-0001-5966-7385)
Seth M. Cohen (ORCID: https://orcid.org/0000-0002-5233-2280)
Grant P. Domecus
Dipendu Mandal (ORCID: https://orcid.org/0000-0003-0971-5478)
Samuel E. Griffin (ORCID: https://orcid.org/0000-0001-7358-9424)

Institutions

University of California San Diego (US)

Publication Details

Journal: Chemical Communications
Published: 2025-01-01
DOI: https://doi.org/10.1039/d5cc02201k
Citations: 2
Primary Topic: Metal-Organic Frameworks: Synthesis and Applications
Type: article
Field-Weighted Citation Impact: 1.07

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article

Selective hydrosilylation of olefins by a two-dimensional Rh(i) low-valent metal–organic framework

Marilena Esposito, Seth M. Cohen, Grant P. Domecus, Dipendu Mandal et al.

Jan 1, 2025

2 citations

Chemical Communications

Metal-Organic Frameworks: Synthesis and Applications

1.07

article

Selective hydrosilylation of olefins by a two-dimensional Rh(i) low-valent metal–organic framework

Marilena Esposito, Seth M. Cohen, Grant P. Domecus, Dipendu Mandal, Samuel E. Griffin

January 1, 2025article en

2 citations

Abstract

Multitopic phosphine ligands combined with Rh(I) or Ir(I) nodes are shown to assemble into low-valent metal-organic frameworks (LVMOFs) with a two-dimensional (2D) topology. The 2D Rh(I) LVMOF exhibits catalytic activity for the hydrosilylation of olefins, functioning in a heterogeneous and selective manner.

Chemical CommunicationsVol. 61(57)

University of California San Diego (US)

Openalex Percentile: Top 23%

Metal-Organic Frameworks: Synthesis and Applications

1.07

DOI Source OpenAlex

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