Cubic ReSTe as a high-performance thermoelectric material

We report thermoelectric properties of sintered samples of undoped, W-doped, and Sb-doped ReSTe crystallized in a cubic MoSBr-type structure. All samples exhibited p-type thermoelectric properties. ReSTe and Re0.993W0.007STe exhibited the largest dimensionless figure of merit ZT, reaching 0.4 at 660 K. This high performance is attributed to a large power factor owing to the degenerate semiconducting state realized by the strong spin–orbit coupling and low lattice thermal conductivity of the sintered samples. Furthermore, electronic band dispersion of ReSTe is almost flat at the bottom of the conduction band, suggesting that n-type ReSTe is expected to exhibit much higher performance than p-type ReSTe.

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Publication Details

Journal
Applied Physics Letters
Published
2025-06-16
DOI
https://doi.org/10.1063/5.0268567
Citations
1
Primary Topic
Advanced Thermoelectric Materials and Devices
Type
article
Field-Weighted Citation Impact
0.52

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article

Cubic ReSTe as a high-performance thermoelectric material

Hironori Ohshima, Yoshihiko Okamoto, Ryutaro Okuma, Youichi Yamakawa et al.
1 citations
Applied Physics Letters
Advanced Thermoelectric Materials and Devices
0.52
article

Cubic ReSTe as a high-performance thermoelectric material

Hironori Ohshima, Yoshihiko Okamoto, Ryutaro Okuma, Youichi Yamakawa, K. Kojima, Chul‐Ho Lee, H. Matsumoto, Hiroto Isomura
article en
1 citations

Abstract

We report thermoelectric properties of sintered samples of undoped, W-doped, and Sb-doped ReSTe crystallized in a cubic MoSBr-type structure. All samples exhibited p-type thermoelectric properties. ReSTe and Re0.993W0.007STe exhibited the largest dimensionless figure of merit ZT, reaching 0.4 at 660 K. This high performance is attributed to a large power factor owing to the degenerate semiconducting state realized by the strong spin–orbit coupling and low lattice thermal conductivity of the sintered samples. Furthermore, electronic band dispersion of ReSTe is almost flat at the bottom of the conduction band, suggesting that n-type ReSTe is expected to exhibit much higher performance than p-type ReSTe.

Applied Physics LettersVol. 126(24)
Nagoya University (JP), National Institute of Advanced Industrial Science and Technology (JP), The University of Tokyo (JP)
Japan Society for the Promotion of Science, Japan Science and Technology Agency, JST-Mirai Program
Openalex Percentile: Top 37%
Advanced Thermoelectric Materials and Devices
0.52
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Cubic ReSTe as a high-performance thermoelectric material — Hironori Ohshima, Yoshihiko Okamoto, et al. · Applied Physics Letters (2025) | TGRS Research Map | TGRS