Synthesis, structure, and properties of twisted π-conjugated molecules featuring three-dimensional π–π interactions in solid states
Thiophene-containing twisted π-conjugated molecules were synthesized by introducing methyl groups to sterically hindered positions. Three-dimensional π-π stacking was observed in the solid state, and the hole-transporting ability up to 1.85 × 10<sup>-4</sup> cm<sup>2</sup> V<sup>-1</sup> s<sup>-1</sup> was confirmed by constructing field effect transistor devices.
Authors
- Mai Nagase (ORCID: https://orcid.org/0000-0002-2568-8425)
- Takashi Hirose (ORCID: https://orcid.org/0000-0002-5351-2101)
- Yasutomo Segawa (ORCID: https://orcid.org/0000-0001-6439-8546)
- Sachiko Nakano
- Ryu Yoshida (ORCID: https://orcid.org/0000-0002-5559-2168)
Institutions
- The Graduate University for Advanced Studies, SOKENDAI (JP)
- Kyoto University (JP)
- Kyoto Bunkyo University (JP)
- Institute for Molecular Science (JP)
- Kyoto University Institute for Chemical Research
Publication Details
- Journal
- Chemical Communications
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5cc02387d
- Citations
- 1
- Primary Topic
- Organic and Molecular Conductors Research
- Type
- article
- Field-Weighted Citation Impact
- 0.43