Quantum transport in the presence of a chiral molecular potential

We investigate quantum transport in a two-dimensional electron system coupled to a chiral molecular potential, demonstrating how molecular chirality and orientation affect charge and spin transport properties. We propose a minimal model for realizing true chiral symmetry breaking on a magnetized surface, with a crucial role played by the tilt angle of the molecular dipole with respect to the surface. For non-zero tilting, we show that the Hall response exhibits clear signatures of chirality-induced effects, in both charge- and spin-resolved observables. Concerning the former, tilted enantiomers produce asymmetric Hall conductances and, even more remarkably, the persistence of this feature in the absence of spin-orbit coupling (SOC) signals how the enantiospecific charge response results from electron scattering off the molecular potential. Concerning spin-resolved observables where SOC plays a relevant role, we reveal that chiral symmetry breaking is crucial in enabling spin-flipping processes.

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Publication Details

Journal
The Journal of Chemical Physics
Published
2025-06-17
DOI
https://doi.org/10.1063/5.0271155
Primary Topic
Quantum and electron transport phenomena
Type
article
Field-Weighted Citation Impact
0.00

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article

Quantum transport in the presence of a chiral molecular potential

Mikhail Lemeshko, Alberto Cappellaro, Ragheed Alhyder
The Journal of Chemical Physics
Quantum and electron transport phenomena
article

Quantum transport in the presence of a chiral molecular potential

Mikhail Lemeshko, Alberto Cappellaro, Ragheed Alhyder
article en

Abstract

We investigate quantum transport in a two-dimensional electron system coupled to a chiral molecular potential, demonstrating how molecular chirality and orientation affect charge and spin transport properties. We propose a minimal model for realizing true chiral symmetry breaking on a magnetized surface, with a crucial role played by the tilt angle of the molecular dipole with respect to the surface. For non-zero tilting, we show that the Hall response exhibits clear signatures of chirality-induced effects, in both charge- and spin-resolved observables. Concerning the former, tilted enantiomers produce asymmetric Hall conductances and, even more remarkably, the persistence of this feature in the absence of spin-orbit coupling (SOC) signals how the enantiospecific charge response results from electron scattering off the molecular potential. Concerning spin-resolved observables where SOC plays a relevant role, we reveal that chiral symmetry breaking is crucial in enabling spin-flipping processes.

The Journal of Chemical PhysicsVol. 162(23)
Institute of Science and Technology Austria (AT), Istituto Nazionale di Fisica Nucleare, Sezione di Padova (IT)
Australian Academy of Science, HORIZON EUROPE Marie Sklodowska-Curie Actions, HORIZON EUROPE European Research Council
Openalex Percentile: Top 89%
Quantum and electron transport phenomena
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