Wear and corrosion resistance of a laser powder bed fused AZ91D magnesium matrix composite with TiC reinforcement

• High-densification TiC/AZ91D composites are fabricated by laser powder bed fusion. • The TiC addition promotes the precipitation of β-Mg 17 Al 12 in the matrix. • The TiC addition improves the hardness and wear resistance of composites. • The wear and corrosion mechanisms of the composites are revealed. The surface performance of magnesium alloys significantly influences their service properties and life in extremely harsh environments. Ceramic modified magnesium alloys cause microstructure refinement and phase variations, affecting their corrosion and wear resistance. In this work, the AZ91D magnesium alloy and a TiC-reinforced magnesium matrix composite were manufactured via laser powder bed fusion (LPBF) to investigate the effect of TiC addition on the relative density, microstructure, wear and electrochemical corrosion resistance of the alloy. The results show that the TiC addition improves the densification of the composite, decreasing the porosity to 0.04 % and promoting the precipitation of Mg 17 Al 12 in the matrix. The grains change from coarse columnar to fine equiaxed ones and a mean size of ∼ 4.2 μm is obtained. The composite exhibits high elastic modulus of 54 ± 1 GPa, microhardness of 108 ± 1 HV 0.2 , and nanohardness of 1.5 ± 0.03 GPa. The wear resistance of the TiC/AZ91D composite increases with a decrease of the coefficient of friction and wear rate. This is because the TiC addition increases the hardness of the alloys and induces oxide formation, and promotes a change from abrasive wear to oxidative wear. The TiC/AZ91D composite exhibits a uniform corrosion film, and high galvanic corrosion resulting from the precipitation of β-Mg 17 Al 12 , leading to a slight decrease in overall corrosion resistance. This work offers insight into the laser additive manufacturing of magnesium matrix composites with good surface properties for applications in extremely harsh environments.

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Publication Details

Journal
Materials & Design
Published
2025-06-17
DOI
https://doi.org/10.1016/j.matdes.2025.114263
Citations
9
Primary Topic
Aluminum Alloys Composites Properties
Type
article
Field-Weighted Citation Impact
6.42

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article

Wear and corrosion resistance of a laser powder bed fused AZ91D magnesium matrix composite with TiC reinforcement

Lixia Xi, J. Eckert, Dongdong Gu, Konda Gokuldoss Prashanth et al.
9 citations
Materials & Design
Aluminum Alloys Composites Properties
6.42
article

Wear and corrosion resistance of a laser powder bed fused AZ91D magnesium matrix composite with TiC reinforcement

Lixia Xi, J. Eckert, Dongdong Gu, Konda Gokuldoss Prashanth, Parthiban Ramasamy, Shilin Tian, Dong Zhang
article en
9 citations

Abstract

• High-densification TiC/AZ91D composites are fabricated by laser powder bed fusion. • The TiC addition promotes the precipitation of β-Mg 17 Al 12 in the matrix. • The TiC addition improves the hardness and wear resistance of composites. • The wear and corrosion mechanisms of the composites are revealed. The surface performance of magnesium alloys significantly influences their service properties and life in extremely harsh environments. Ceramic modified magnesium alloys cause microstructure refinement and phase variations, affecting their corrosion and wear resistance. In this work, the AZ91D magnesium alloy and a TiC-reinforced magnesium matrix composite were manufactured via laser powder bed fusion (LPBF) to investigate the effect of TiC addition on the relative density, microstructure, wear and electrochemical corrosion resistance of the alloy. The results show that the TiC addition improves the densification of the composite, decreasing the porosity to 0.04 % and promoting the precipitation of Mg 17 Al 12 in the matrix. The grains change from coarse columnar to fine equiaxed ones and a mean size of ∼ 4.2 μm is obtained. The composite exhibits high elastic modulus of 54 ± 1 GPa, microhardness of 108 ± 1 HV 0.2 , and nanohardness of 1.5 ± 0.03 GPa. The wear resistance of the TiC/AZ91D composite increases with a decrease of the coefficient of friction and wear rate. This is because the TiC addition increases the hardness of the alloys and induces oxide formation, and promotes a change from abrasive wear to oxidative wear. The TiC/AZ91D composite exhibits a uniform corrosion film, and high galvanic corrosion resulting from the precipitation of β-Mg 17 Al 12 , leading to a slight decrease in overall corrosion resistance. This work offers insight into the laser additive manufacturing of magnesium matrix composites with good surface properties for applications in extremely harsh environments.

Materials & DesignVol. 256
Tallinn University of Technology (EE), Austrian Academy of Sciences (AT), Montanuniversität Leoben (AT), Erich Schmid Institute of Materials Science (AT), Vellore Institute of Technology University (IN), Nanjing University of Aeronautics and Astronautics (CN)
Innovative Research Group Project of the National Natural Science Foundation of China, National Natural Science Foundation of China, Jiangsu Provincial Key Research and Development Program, Science and Technology Support Program of Jiangsu Province, Key Technologies Research and Development Program, National Key Research and Development Program of China, Fundamental Research Funds for the Central Universities
Openalex Percentile: Top 3%
Aluminum Alloys Composites Properties
6.42
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