Radical-polar crossover cyclization: visible-light-induced synthesis of γ-alkylated 1,1-disubstituted cyclopropanes <i>via</i> 1,6-hydrogen atom transfer
A visible-light-induced radical-polar crossover cyclization (RPCC) reaction between homoallylic substrates and sulfamate esters for the synthesis of γ-alkylated 1,1-disubstituted cyclopropanes via 1,6-HAT processes has been reported.
Authors
- Min Liao (ORCID: https://orcid.org/0000-0001-6777-8579)
- Zeyu Tian (ORCID: https://orcid.org/0000-0002-1661-7860)
- Meiling Ye (ORCID: https://orcid.org/0009-0005-0166-0048)
- Yong Wu (ORCID: https://orcid.org/0000-0003-0719-4963)
- Hang Wang (ORCID: https://orcid.org/0000-0001-6021-739X)
- Zhongzhen Yang (ORCID: https://orcid.org/0000-0003-3402-0088)
Institutions
- Sichuan University (CN)
- West China Hospital of Sichuan University (CN)
Publication Details
- Journal
- Organic Chemistry Frontiers
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5qo00670h
- Citations
- 1
- Primary Topic
- Cyclopropane Reaction Mechanisms
- Type
- article
- Field-Weighted Citation Impact
- 0.94