(η<sup>4</sup>-Trimethylenemethane)(1,1,1-tris{[bis(4-methoxyphenyl)phosphanyl]methyl}ethane)ruthenium(II) diethyl ether hemisolvate
The title compound, [Ru(C<sub>47</sub>H<sub>51</sub>O<sub>6</sub>P<sub>3</sub>)(C<sub>4</sub>H<sub>6</sub>)]·0.5C<sub>4</sub>H<sub>10</sub>O, consists of an Ru<sup>II</sup> atom coordinated by 1,1,1-tris-{[bis-(4-meth-oxy-phen-yl)phosphan-yl]meth-yl}ethane in κ<sup>3</sup>-coordination mode and an η<sup>4</sup>-coordinating tri-methyl-ene-methane ligand. The complex mol-ecule is co-crystallized with a diethyl ether solvent mol-ecule. A half diethyl ether mol-ecule was considered, whereas additional disordered solvent mol-ecules were removed from the diffraction data with the SQUEEZE procedure in <i>PLATON</i> [Spek (2015 ▸). <i>Acta Cryst</i>. C<b>71</b>, 9-18].
Authors
- Carolin A. M. Stein
- Matthias Beller (ORCID: https://orcid.org/0000-0001-5709-0965)
- Henrik Junge (ORCID: https://orcid.org/0000-0002-7603-1984)
- Elisabetta Alberico (ORCID: https://orcid.org/0000-0002-1143-6032)
- Anke Spannenberg
Institutions
- Leibniz Institute for Catalysis (DE)
- Istituto di Chimica Biomolecolare (IT)
Publication Details
- Journal
- IUCrData
- Published
- 2025-06-17
- DOI
- https://doi.org/10.1107/s2414314625005243
- Primary Topic
- Asymmetric Hydrogenation and Catalysis
- Type
- article
- Field-Weighted Citation Impact
- 0.00