1-[(2-Bromophenyl)diphenylmethyl]-3-(trifluoromethyl)-1<i>H</i>-pyrazole–1-(triphenylmethyl)-3-(trifluoromethyl)-1<i>H</i>-pyrazole (0.638:0.362)
In the title compound, 0.638C<sub>23</sub>H<sub>16</sub>BrF<sub>3</sub>N<sub>2</sub>·0.362C<sub>23</sub>H<sub>17</sub>F<sub>3</sub>N<sub>2</sub>, the Br atom has been partially replaced by an H atom by reaction with NaH. In the crystal, pairwise C-H⋯Br hydrogen bonds link the mol-ecules into centrosymmetric dimers, enclosing <i>R</i> <sup>2</sup> <sub>2</sub>(16) ring motifs. A Hirshfeld surface analysis indicates that the most important contributions for the crystal packing are from H⋯H (40.1%), H⋯F/F⋯H (21.4%) and H⋯C/C⋯H (18.9%) inter-actions.
Authors
- Jamal Lasri (ORCID: https://orcid.org/0000-0002-8949-8698)
- Aida I. Samigullina (ORCID: https://orcid.org/0000-0002-6791-9973)
- Alebel N. Belay (ORCID: https://orcid.org/0000-0003-4175-5656)
- Tuncer Hökelek (ORCID: https://orcid.org/0000-0002-8602-4382)
- Firudin I. Guseinov (ORCID: https://orcid.org/0000-0002-6769-0232)
- Khudayar I. Hasanov
- Tahir A. Javadzade (ORCID: https://orcid.org/0000-0003-3327-4430)
- Sahil Z. Hamidov
Institutions
- A. N. Kosygin Moscow State Textile University (RU)
- Khazar University (AZ)
- King Abdulaziz University (SA)
- Azerbaijan Medical University (AZ)
- Azerbaijan Technical University (AZ)
- Western Caspian University (AZ)
- N.D. Zelinsky Institute of Organic Chemistry (RU)
- Bahir Dar University (ET)
- Hacettepe University (TR)
Publication Details
- Journal
- IUCrData
- Published
- 2025-06-17
- DOI
- https://doi.org/10.1107/s2414314625004663
- Primary Topic
- Synthesis and biological activity
- Type
- article
- Field-Weighted Citation Impact
- 0.00
Funders
- Hacettepe Üniversitesi