Low-carbon MgO/hydromagnesite binders – effect of moisture state on the evolution of mechanical properties

We studied the mechanical properties of MgO/hydromagnesite mortars cured at 20 °C both in humid (98 %RH) and dry (57 %RH) environments. The linear storage Young's modulus was determined with quasi-static loading and dynamically by SIngle MOde Resonance Ultrasound Spectroscopy (SIMORUS) measurements. We measured the corresponding loss modulus and the nonlinear counterpart of the storage modulus. Humid environment adversely affected the evolution of the elastic properties, i.e. it caused a reduction of the linear storage Young's modulus and an increase of its nonlinear counterpart, the latter being a proxy of microstructural heterogeneity and potential damage. On the other hand, mortars cured at 57 %RH experienced a monotonous growth of the linear storage Young's modulus and decrease of the loss modulus. Similar trends were observed for compressive strength. We postulate that the lowering of mechanical properties upon moisture uptake is due to the intrinsic effect of adsorbed water on the microstructure.

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Publication Details

Journal
Cement and Concrete Research
Published
2025-06-16
DOI
https://doi.org/10.1016/j.cemconres.2025.107966
Citations
2
Primary Topic
Magnesium Oxide Properties and Applications
Type
article
Field-Weighted Citation Impact
1.04
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article

Low-carbon MgO/hydromagnesite binders – effect of moisture state on the evolution of mechanical properties

Michele Griffa, Alexander German, Frank Winnefeld, Mateusz Wyrzykowski et al.
2 citations
Cement and Concrete Research
Magnesium Oxide Properties and Applications
1.04
article

Low-carbon MgO/hydromagnesite binders – effect of moisture state on the evolution of mechanical properties

Michele Griffa, Alexander German, Frank Winnefeld, Mateusz Wyrzykowski, Nikolajs Toropovs, Pietro Lura, Ye Zhu
article en
2 citations

Abstract

We studied the mechanical properties of MgO/hydromagnesite mortars cured at 20 °C both in humid (98 %RH) and dry (57 %RH) environments. The linear storage Young's modulus was determined with quasi-static loading and dynamically by SIngle MOde Resonance Ultrasound Spectroscopy (SIMORUS) measurements. We measured the corresponding loss modulus and the nonlinear counterpart of the storage modulus. Humid environment adversely affected the evolution of the elastic properties, i.e. it caused a reduction of the linear storage Young's modulus and an increase of its nonlinear counterpart, the latter being a proxy of microstructural heterogeneity and potential damage. On the other hand, mortars cured at 57 %RH experienced a monotonous growth of the linear storage Young's modulus and decrease of the loss modulus. Similar trends were observed for compressive strength. We postulate that the lowering of mechanical properties upon moisture uptake is due to the intrinsic effect of adsorbed water on the microstructure.

Cement and Concrete ResearchVol. 197
ETH Zurich (CH), Institute for Biomedical Engineering (CH), Swiss Federal Laboratories for Materials Science and Technology (CH)
Openalex Percentile: Top 24%
Magnesium Oxide Properties and Applications
1.04
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