Mode-coupling theory of the glass transition for a liquid in a periodic potential

We derive a microscopic theory for the structural dynamics in the vicinity of the glass transition for a liquid exposed to a one-dimensional periodic potential. The periodic potential breaks translational invariance; in particular, the density exhibits a periodic modulation. Using techniques familiar from solid-state theory, we define generalized intermediate scattering functions from fluctuating densities in wave-vector space. Exact equations of motion are derived within the Mori-Zwanzig projection-operator formalism reflecting the residual lattice symmetries. Due to the lack of rotational symmetry it is necessary to split the currents into components parallel and perpendicular to the modulation. We provide a closure of the equations in terms of a mode-coupling approximation for the force kernel. The theory reflects the usual analytic properties of correlation functions and encodes all phenomena known for mode-coupling theories. We prove that the theory reduces to the conventional mode-coupling theory in the case of vanishing amplitude of the modulation.

Authors

Institutions

Publication Details

Journal
Physical review. E
Published
2025-06-16
DOI
https://doi.org/10.1103/ks5t-xtvd
Citations
1
Primary Topic
Material Dynamics and Properties
Type
article
Field-Weighted Citation Impact
0.52

Funders

Controls
|||
ALL TIME
JAN
FEB
MAR
APR
MAY
JUN
JUL
AUG
SEP
OCT
article

Mode-coupling theory of the glass transition for a liquid in a periodic potential

Thomas Franosch, Michele Caraglio, Vincent Krakoviack, Abolfazl Ahmadirahmat
1 citations
Physical review. E
Material Dynamics and Properties
0.52
article

Mode-coupling theory of the glass transition for a liquid in a periodic potential

Thomas Franosch, Michele Caraglio, Vincent Krakoviack, Abolfazl Ahmadirahmat
article en
1 citations

Abstract

We derive a microscopic theory for the structural dynamics in the vicinity of the glass transition for a liquid exposed to a one-dimensional periodic potential. The periodic potential breaks translational invariance; in particular, the density exhibits a periodic modulation. Using techniques familiar from solid-state theory, we define generalized intermediate scattering functions from fluctuating densities in wave-vector space. Exact equations of motion are derived within the Mori-Zwanzig projection-operator formalism reflecting the residual lattice symmetries. Due to the lack of rotational symmetry it is necessary to split the currents into components parallel and perpendicular to the modulation. We provide a closure of the equations in terms of a mode-coupling approximation for the force kernel. The theory reflects the usual analytic properties of correlation functions and encodes all phenomena known for mode-coupling theories. We prove that the theory reduces to the conventional mode-coupling theory in the case of vanishing amplitude of the modulation.

Physical review. EVol. 112(1)
École Normale Supérieure de Lyon (FR), Universität Innsbruck (AT), Université Clermont Auvergne (FR), Institut de Chimie (FR), Laboratoire de Chimie (FR), East China Normal University (CN)
Austrian Science Fund
Openalex Percentile: Top 37%
Material Dynamics and Properties
0.52
AI Navigator

Ask Laika to Summarize, Analyze, and Connect papers live on the map.

Summarize Papers & Methodologies

Extract key findings, datasets, and comparative methods across publications.

Benchmark Rankings & Visual Analytics

Rank top research institutions, authors, funders, topics, and journals by Field-Weighted Citation Impact (FWCI) and paper volume with instant charts.

Connect Distant Disciplines

Bridge topological clusters on the map to find hidden collaborative intersections.