Optimizing the transport and redox properties of PVDF-based electrolytes through structural design of residual solvents
In poly(vinylidene fluoride) (PVDF)-based electrolytes, residual solvents play a crucial role in determining the electrolyte performance. Herein, the influence of various residual solvents on electrolyte properties is investigated through atomistic modeling. It is found that fluorination and reduced molecular volume can facilitate fast ionic diffusion and enhanced cycling stability.
Authors
- Yan‐Bing He (ORCID: https://orcid.org/0000-0001-5787-5498)
- Yaoshu Xie (ORCID: https://orcid.org/0000-0002-0725-0091)
- Ke Yang (ORCID: https://orcid.org/0000-0002-8389-8228)
- Shendong Tan
- Tingzheng Hou (ORCID: https://orcid.org/0000-0002-7163-2561)
- Zihui Li (ORCID: https://orcid.org/0000-0003-0865-4634)
- Jia Li (ORCID: https://orcid.org/0000-0002-4434-7888)
- Yimei Zhu (ORCID: https://orcid.org/0000-0002-1638-7217)
- Bochun Liang (ORCID: https://orcid.org/0009-0009-2822-7067)
- Chaoyuan Ji
Institutions
- City University of Hong Kong (HK)
- University Town of Shenzhen (CN)
- Tsinghua–Berkeley Shenzhen Institute (CN)
Publication Details
- Journal
- Chemical Communications
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5cc01099c
- Citations
- 2
- Primary Topic
- Advanced Battery Materials and Technologies
- Type
- article
- Field-Weighted Citation Impact
- 1.46
Funders
- National Natural Science Foundation of China
- National Key Research and Development Program of China