Synthesis, Structure, and <sup>199</sup> Hg Chemical Shifts of Mercury 1,5,9‐trimesityldipyrromethene ( <sup>Mes</sup> DPM) Complexes
In this work, we describe the easy synthesis of mercury complexes with the 1,5,9-trimesityldipyrromethene (<sup>Mes</sup>DPM) ligand. The compounds were characterized using standard analytic methods such as NMR, IR, as well as UV/Vis spectroscopy. The molecular structures in solid state were determined by single-crystal X-ray diffraction analysis (SC-XRD) experiments. In addition, the <sup>199</sup>Hg NMR chemical shifts were determined by measurements and quantum chemical calculations.
Authors
- Jochen Autschbach (ORCID: https://orcid.org/0000-0001-9392-877X)
- Leonardo A. Schenberg (ORCID: https://orcid.org/0000-0002-1670-0373)
- Lucas C. Ducati (ORCID: https://orcid.org/0000-0002-6539-4325)
- Trevor W. Hayton (ORCID: https://orcid.org/0000-0003-4370-1424)
- Lukas Erlemeier (ORCID: https://orcid.org/0009-0006-8286-7901)
- Phoebe R. Hertler
- Guang Wu (ORCID: https://orcid.org/0000-0001-7257-6648)
- Xiulan Xie
- Carsten von Hänisch
Institutions
- Buffalo State University (US)
- University of California, Santa Barbara (US)
- Philipps University of Marburg (DE)
- Universidade de São Paulo (BR)
- Fundo Brasil (BR)
- University at Buffalo, State University of New York (US)
Publication Details
- Journal
- Chemistry - A European Journal
- Published
- 2025-06-16
- DOI
- https://doi.org/10.1002/chem.202501460
- Primary Topic
- Porphyrin and Phthalocyanine Chemistry
- Type
- article
- Field-Weighted Citation Impact
- 0.00
Funders
- National Science Foundation
- Deutscher Akademischer Austauschdienst
- Deutsche Forschungsgemeinschaft
- Fundação de Amparo à Pesquisa do Estado de São Paulo
- Coordenação de Aperfeiçoamento de Pessoal de Nível Superior
- Ministério da Ciência, Tecnologia e Inovação
- Conselho Nacional de Desenvolvimento Científico e Tecnológico
- University of California, Santa Barbara
- University at Buffalo
- Division of Chemistry