Alkaline gelatinized locust bean gum: Alternative depressant for pyroxene and talc in Platreef ore

• At 100g/t, LBG yielded higher Pt grade and recovery than CMC. • LBG yielded faster Pt, Pd, and Rh kinetics than CMC at all dosages tested. • Both LBG and CMC recovered <20% of pyroxene, and talc at all dosages tested. • Gangue recovery vs mass pull plots were linear, so both depressants were selective. • LBG depression efficacy on all gangue studied increased as its dosage increased. Carboxymethyl cellulose (CMC) is a common depressant used in flotation. However, CMC has a high negative charge density. This results in stronger electrostatic repulsion on negatively charged minerals. Also, it is susceptible to pulp ionic strength. Hence, the high dose requirements for effective depression. This is detrimental as CMC destabilizes the froth at high dosages. Locust bean gum (LBG) brings attractive attributes like low charge density and insensitivity to pulp ionic strength. Therefore, this paper explored the feasibility of using alkaline gelatinized LBG as a CMC alternative depressant for pyroxene and talc. Bench flotation tests were conducted using Platreef ore to compare LBG and CMC's performance at 25g/t, 50g/t, and 100g/t. This study showed that LBG and CMC yielded comparable pyroxene and talc depression (>80%) at all dosages tested. Furthermore, at 100g/t, the respective Pt recoveries of 88% and 83% illustrated that LBG was more effective than CMC at allowing Pt to float unhindered. Additionally, zeta potential measurements were conducted in the presence and absence of the depressant to establish the adsorption mechanisms. The zeta potential results showed that CMC and LBG adsorption onto pyroxene and talc surfaces were different due to their structural and ionic strength differences.

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Publication Details

Journal
South African Journal of Chemical Engineering
Published
2025-06-16
DOI
https://doi.org/10.1016/j.sajce.2025.06.008
Citations
1
Primary Topic
Polysaccharides Composition and Applications
Type
article
Field-Weighted Citation Impact
1.16
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article

Alkaline gelatinized locust bean gum: Alternative depressant for pyroxene and talc in Platreef ore

Antoine F. Mulaba‐Bafubiandi, Walter Amos Ngobeni
1 citations
South African Journal of Chemical Engineering
Polysaccharides Composition and Applications
1.16
article

Alkaline gelatinized locust bean gum: Alternative depressant for pyroxene and talc in Platreef ore

Antoine F. Mulaba‐Bafubiandi, Walter Amos Ngobeni
article en
1 citations

Abstract

• At 100g/t, LBG yielded higher Pt grade and recovery than CMC. • LBG yielded faster Pt, Pd, and Rh kinetics than CMC at all dosages tested. • Both LBG and CMC recovered <20% of pyroxene, and talc at all dosages tested. • Gangue recovery vs mass pull plots were linear, so both depressants were selective. • LBG depression efficacy on all gangue studied increased as its dosage increased. Carboxymethyl cellulose (CMC) is a common depressant used in flotation. However, CMC has a high negative charge density. This results in stronger electrostatic repulsion on negatively charged minerals. Also, it is susceptible to pulp ionic strength. Hence, the high dose requirements for effective depression. This is detrimental as CMC destabilizes the froth at high dosages. Locust bean gum (LBG) brings attractive attributes like low charge density and insensitivity to pulp ionic strength. Therefore, this paper explored the feasibility of using alkaline gelatinized LBG as a CMC alternative depressant for pyroxene and talc. Bench flotation tests were conducted using Platreef ore to compare LBG and CMC's performance at 25g/t, 50g/t, and 100g/t. This study showed that LBG and CMC yielded comparable pyroxene and talc depression (>80%) at all dosages tested. Furthermore, at 100g/t, the respective Pt recoveries of 88% and 83% illustrated that LBG was more effective than CMC at allowing Pt to float unhindered. Additionally, zeta potential measurements were conducted in the presence and absence of the depressant to establish the adsorption mechanisms. The zeta potential results showed that CMC and LBG adsorption onto pyroxene and talc surfaces were different due to their structural and ionic strength differences.

South African Journal of Chemical EngineeringVol. 53
University of Johannesburg (ZA), Sasol (South Africa) (ZA)
Zero hunger
Openalex Percentile: Top 21%
Polysaccharides Composition and Applications
1.16
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