Synthesis of Substituted 2-Arylimino-3-oxopropanenitriles and 2-(Arylimino)propanedinitriles by Oxidative Coupling of Primary Aromatic Amines with Aroylacetonitriles and Malononitrile

Oxidative coupling of aromatic amines with 3-aryl-3-oxopropanenitriles in the presence of selenium(IV) oxide gave the corresponding 2-arylimino-3-oxopropanenitriles. Similar reactions of arylamines with propanedinitrile afforded 2-(arylimino)propanedinitriles.

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Publication Details

Journal
Russian Journal of Organic Chemistry
Published
2025-04-01
DOI
https://doi.org/10.1134/s1070428025601074
Primary Topic
Asymmetric Synthesis and Catalysis
Type
article
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article

Synthesis of Substituted 2-Arylimino-3-oxopropanenitriles and 2-(Arylimino)propanedinitriles by Oxidative Coupling of Primary Aromatic Amines with Aroylacetonitriles and Malononitrile

O. Yu. Slabko, Andrey V. Kachanov, M. A. Kucheshov
Russian Journal of Organic Chemistry
Asymmetric Synthesis and Catalysis
article

Synthesis of Substituted 2-Arylimino-3-oxopropanenitriles and 2-(Arylimino)propanedinitriles by Oxidative Coupling of Primary Aromatic Amines with Aroylacetonitriles and Malononitrile

O. Yu. Slabko, Andrey V. Kachanov, M. A. Kucheshov
article en

Abstract

Oxidative coupling of aromatic amines with 3-aryl-3-oxopropanenitriles in the presence of selenium(IV) oxide gave the corresponding 2-arylimino-3-oxopropanenitriles. Similar reactions of arylamines with propanedinitrile afforded 2-(arylimino)propanedinitriles.

Russian Journal of Organic ChemistryVol. 61(4)
Far Eastern Federal University (RU)
Clean water and sanitation
Openalex Percentile: Top 90%
Asymmetric Synthesis and Catalysis
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