Reaction of Fluorodinitroacetonitrile with Nitrile Oxides

The reaction of 2-fluoro-2,2-dinitroacetonitrile with nitrile oxides gave 3-aryl(methyl)-5-(fluoro­dinitromethyl)-1,2,4-oxadiazoles which reacted with ethanolic potassium hydroxide to afford 3-aryl(methyl)-1,2,4-oxadiazol-5-ols as a result of elimination of the fluorodinitromethyl group as fluoro(dinitro)methane potassium salt.

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Publication Details

Journal
Russian Journal of Organic Chemistry
Published
2025-04-01
DOI
https://doi.org/10.1134/s1070428025600639
Primary Topic
Chemical Reactions and Mechanisms
Type
article
Field-Weighted Citation Impact
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article

Reaction of Fluorodinitroacetonitrile with Nitrile Oxides

Evgenia Utyaganova, А. Г. Тырков, Е. А. Yurtaeva
Russian Journal of Organic Chemistry
Chemical Reactions and Mechanisms
article

Reaction of Fluorodinitroacetonitrile with Nitrile Oxides

Evgenia Utyaganova, А. Г. Тырков, Е. А. Yurtaeva
article en

Abstract

The reaction of 2-fluoro-2,2-dinitroacetonitrile with nitrile oxides gave 3-aryl(methyl)-5-(fluoro­dinitromethyl)-1,2,4-oxadiazoles which reacted with ethanolic potassium hydroxide to afford 3-aryl(methyl)-1,2,4-oxadiazol-5-ols as a result of elimination of the fluorodinitromethyl group as fluoro(dinitro)methane potassium salt.

Russian Journal of Organic ChemistryVol. 61(4)
Volgograd State Medical University (RU), Astrakhan Tatischev State University (RU), Pyatigorsk Medical and Pharmaceutical Institute - branch of Volgograd State Medical University (RU)
Openalex Percentile: Top 86%
Chemical Reactions and Mechanisms
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