Lithium extraction using zirconium oxide coated lithium manganese oxide ion-exchange adsorbents

Lithium extraction from sedimentary brines using spinel lithium manganese oxide, Li<sub>1.6</sub>Mn<sub>1.6</sub>O<sub>4</sub>, is challenging because of the presence of dissolved organic compounds, resulting in manganese reduction and loss. Coating the sorbent with a 7.5 nm layer of zirconium dioxide decreased manganese loss by approximately 50%, while not substantially impacting its adsorption capacity and selectivity, thereby increasing its usable life.

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Publication Details

Journal
Chemical Communications
Published
2025-01-01
DOI
https://doi.org/10.1039/d5cc02392k
Citations
1
Primary Topic
Extraction and Separation Processes
Type
article
Field-Weighted Citation Impact
0.71

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Lithium extraction using zirconium oxide coated lithium manganese oxide ion-exchange adsorbents

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Extraction and Separation Processes
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article

Lithium extraction using zirconium oxide coated lithium manganese oxide ion-exchange adsorbents

Fangshuai Wu, Ning Chen, Daniel S. Alessi, Salman Safari, Brendan Bishop, Ashkan Zolfaghari, Leslie J. Robbins, Karthik Ramachandran Shivakumar
article en
1 citations

Abstract

Lithium extraction from sedimentary brines using spinel lithium manganese oxide, Li<sub>1.6</sub>Mn<sub>1.6</sub>O<sub>4</sub>, is challenging because of the presence of dissolved organic compounds, resulting in manganese reduction and loss. Coating the sorbent with a 7.5 nm layer of zirconium dioxide decreased manganese loss by approximately 50%, while not substantially impacting its adsorption capacity and selectivity, thereby increasing its usable life.

Chemical CommunicationsVol. 61(59)
Suncor Energy (Canada) (CA), University of Alberta (CA), University of Regina (CA), University of Saskatchewan (CA), Canadian Light Source (Canada) (CA)
Canada First Research Excellence Fund, Natural Sciences and Engineering Research Council of Canada
Openalex Percentile: Top 31%
Extraction and Separation Processes
0.71
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