Spatial Mapping of OH Radicals Produced by Electric Discharge in Hydrodynamic Cavitation Cloud

As strong oxidizers, OH radicals are crucial for water treatment applications involving plasma-liquid interactions. Hydrodynamic cavitation-based systems show promise for disinfection and micropollutant removal at flow rates of several m<sup>3</sup>/h. Knowledge of the spatial distribution of OH is limited. However, this is vital for enhancing system efficiency. This study maps the spatial distribution of OH generated by electric discharge in a hydrodynamic cavitation cloud. Using Luminol as a chemiluminescent probe, the study addresses challenges related to probe stability and luminescence lifetime in a dynamic cavitation environment. Luminescence decay time was assessed with a fast-frame camera, and spatial mapping was conducted by using an ICCD camera with an optical filter. Strong emission was observed at the collapsing end of the cavitation cloud and within the discharge channel, indicating the production and transport of OH into the liquid.

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Publication Details

Journal
The Journal of Physical Chemistry Letters
Published
2025-06-13
DOI
https://doi.org/10.1021/acs.jpclett.5c00979
Citations
2
Primary Topic
Plasma Applications and Diagnostics
Type
article
Field-Weighted Citation Impact
2.72

Funders

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article

Spatial Mapping of OH Radicals Produced by Electric Discharge in Hydrodynamic Cavitation Cloud

Pavel Rudolf, Blahoslav Maršálek, David Trunec, Pavel Šťahel et al.
2 citations
The Journal of Physical Chemistry Letters
Plasma Applications and Diagnostics
2.72
article

Spatial Mapping of OH Radicals Produced by Electric Discharge in Hydrodynamic Cavitation Cloud

Pavel Rudolf, Blahoslav Maršálek, David Trunec, Pavel Šťahel, Ján Čech, Lubomı́r Prokeš, Radek Horňák
article en
2 citations

Abstract

As strong oxidizers, OH radicals are crucial for water treatment applications involving plasma-liquid interactions. Hydrodynamic cavitation-based systems show promise for disinfection and micropollutant removal at flow rates of several m<sup>3</sup>/h. Knowledge of the spatial distribution of OH is limited. However, this is vital for enhancing system efficiency. This study maps the spatial distribution of OH generated by electric discharge in a hydrodynamic cavitation cloud. Using Luminol as a chemiluminescent probe, the study addresses challenges related to probe stability and luminescence lifetime in a dynamic cavitation environment. Luminescence decay time was assessed with a fast-frame camera, and spatial mapping was conducted by using an ICCD camera with an optical filter. Strong emission was observed at the collapsing end of the cavitation cloud and within the discharge channel, indicating the production and transport of OH into the liquid.

The Journal of Physical Chemistry LettersVol. 16(25)
Czech Academy of Sciences (CZ), Masaryk University (CZ), Czech Academy of Sciences, Institute of Botany (CZ), Brno University of Technology (CZ)
Grantová Agentura České Republiky
Openalex Percentile: Top 10%
Plasma Applications and Diagnostics
2.72
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Spatial Mapping of OH Radicals Produced by Electric Discharge in Hydrodynamic Cavitation Cloud — Pavel Rudolf, Blahoslav Maršálek, et al. · The Journal of Physical Chemistry Letters (2025) | TGRS Research Map | TGRS