Effective and Realistic Strategies for Large-Scale Liquid Hydrogen Production

The excessive use of fossil fuels could bring about a global environmental crisis. Transitioning from a carbon-based to a hydrogen-based economy is an important way to realize the low-carbon energy transition. The key to this economy transformation lies in the efficient utilization of hydrogen. Hydrogen liquefaction is an efficient technology for the transportation and storage of hydrogen, and the liquid hydrogen produced is also a direct feedstock for many important fields. Large-scale liquefaction of hydrogen has not been commercialized due to its high energy consumption (>10 kWh/kgLH2) and low efficiency (<30%). However, conceptual designs for hydrogen liquefaction with a low energy consumption (about 6.4 kWh/kgLH2) and high efficiency (>40%) are frequently reported in the existing literature. Therefore, in this paper, the production process of liquid hydrogen is reviewed from three aspects, which are hydrogen pre-cooling, hydrogen cryo-cooling, and ortho-para hydrogen (OPH) conversion. The focus is to summarize effective and realistic hydrogen liquefaction schemes in the existing studies to provide process guidance for the subsequent practical production of liquid hydrogen. The development of open and closed refrigeration cycles for hydrogen pre-cooling is reviewed following the lead of pre-coolant types. The implementation methods of structural optimization of different hydrogen cryo-cooling cycles are clarified and the performance improvements achieved are compared. Different modes of OPH conversion are presented and their realization in simulation and practical applications is summarized. Finally, subjective recommendations are given regarding the content of the review.