Current-Induced Evolving Mechanical Properties, Formation of Defects, and Interfacial Intermetallic Growth in the Interconnects Bonded with Au Wire

Continuously improving chip integration and increasing packaging density increase the risk of performance degradation and electromigration (EM) failure on the bonding interface during electrical transmission. While EM failure, as a time-accumulated failure, is one core challenge of semiconductor reliability and is particularly severe in highly integrated chips. However, the polarity differences existing in commercial devices and the evolving polarity characteristics of microscale bonding interfaces have not been well addressed. Therefore, this study describes the polarity effects of EM in a commercial chip-end Au-Al system and reveals the evolution of intermetallic compound (IMC) growth at bonding interfaces under high-density currents. An EM simulation model is developed to jointly analyze the influence of current-induced polarity effects on the evolution of material migration and IMC growth together with experimental results. Specifically, under the influence of the polarity effect, the thickness of the anode IMC layer is approximately twice as thick as that of the cathode. The IMC thickness on both sides is much thicker than the center under the influence of the size effect. Unlike previous studies, the IMC at the commercial bonding interface is mainly the Al<sub>3</sub>Au<sub>8</sub> phase in columnar crystal morphology and the α-AlAu<sub>4</sub> phase in nanocrystalline morphology, with the former being mainly located in the middle region of the IMC layer, while the latter is mainly located in the edge region of the IMC layer. Due to the overgrowth of the IMC layer, the tensile mechanical properties of the interface are degraded, and the failure mode transforms from a single neck fracture to a predominant joint detachment. This study complements and improves the research framework of Au/Al interface IMC at commercial chip joints and lays a theoretical foundation for the development of semiconductor chips toward high integration, high density, and high reliability.

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Publication Details

Journal
ACS Applied Materials & Interfaces
Published
2025-06-13
DOI
https://doi.org/10.1021/acsami.5c03751
Citations
1
Primary Topic
Electronic Packaging and Soldering Technologies
Type
article
Field-Weighted Citation Impact
0.73

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article

Current-Induced Evolving Mechanical Properties, Formation of Defects, and Interfacial Intermetallic Growth in the Interconnects Bonded with Au Wire

Qinsong Bi, Manal S. Ebaid, Hassan Algadi, Shanju Zheng et al.
1 citations
ACS Applied Materials & Interfaces
Electronic Packaging and Soldering Technologies
0.73
article

Current-Induced Evolving Mechanical Properties, Formation of Defects, and Interfacial Intermetallic Growth in the Interconnects Bonded with Au Wire

Qinsong Bi, Manal S. Ebaid, Hassan Algadi, Shanju Zheng, Dapeng Yang, Jiaheng Zhang, Yuxi Luo, Quanfeng He, Dengquan Chen, Xiaojing Wang, Xiaohong Yuan, Zhanhu Guo
article en
1 citations

Abstract

Continuously improving chip integration and increasing packaging density increase the risk of performance degradation and electromigration (EM) failure on the bonding interface during electrical transmission. While EM failure, as a time-accumulated failure, is one core challenge of semiconductor reliability and is particularly severe in highly integrated chips. However, the polarity differences existing in commercial devices and the evolving polarity characteristics of microscale bonding interfaces have not been well addressed. Therefore, this study describes the polarity effects of EM in a commercial chip-end Au-Al system and reveals the evolution of intermetallic compound (IMC) growth at bonding interfaces under high-density currents. An EM simulation model is developed to jointly analyze the influence of current-induced polarity effects on the evolution of material migration and IMC growth together with experimental results. Specifically, under the influence of the polarity effect, the thickness of the anode IMC layer is approximately twice as thick as that of the cathode. The IMC thickness on both sides is much thicker than the center under the influence of the size effect. Unlike previous studies, the IMC at the commercial bonding interface is mainly the Al<sub>3</sub>Au<sub>8</sub> phase in columnar crystal morphology and the α-AlAu<sub>4</sub> phase in nanocrystalline morphology, with the former being mainly located in the middle region of the IMC layer, while the latter is mainly located in the edge region of the IMC layer. Due to the overgrowth of the IMC layer, the tensile mechanical properties of the interface are degraded, and the failure mode transforms from a single neck fracture to a predominant joint detachment. This study complements and improves the research framework of Au/Al interface IMC at commercial chip joints and lays a theoretical foundation for the development of semiconductor chips toward high integration, high density, and high reliability.

ACS Applied Materials & InterfacesVol. 17(25)
Kunming University of Science and Technology (CN), Northern Border University (SA), Northumbria University (GB), Jiangsu University of Science and Technology (CN), Material (Belgium) (BE), Kunming Institute of Precious Metals (CN), Najran University (SA)
Najran University
Openalex Percentile: Top 27%
Electronic Packaging and Soldering Technologies
0.73
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