Enhanced electrocatalytic reduction of hexavalent chromium with reduced pH dependence <i>via</i> alternating potential polarization using a polyaniline–chitosan composite electrode

The slow kinetics and strong pH dependence of hexavalent chromium, Cr(VI), electroreduction pose significant challenges for efficient remediation. Herein, an innovative alternating potential technique coupled with a polyaniline/chitosan composite electrode is developed to achieve rapid Cr(VI) removal (up to 17.8 h<sup>-1</sup> at pH ∼ 2.0) while mitigating pH sensitivity (1.2 h<sup>-1</sup> at pH ∼ 5.0).

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Publication Details

Journal
Chemical Communications
Published
2025-01-01
DOI
https://doi.org/10.1039/d5cc03007b
Citations
1
Primary Topic
Electrochemical Analysis and Applications
Type
article
Field-Weighted Citation Impact
0.52

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article

Enhanced electrocatalytic reduction of hexavalent chromium with reduced pH dependence via alternating potential polarization using a polyaniline–chitosan composite electrode

Rongliang Qiu, Yetao Tang, Ye Xiao, Huihui Zheng et al.
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Electrochemical Analysis and Applications
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article

Enhanced electrocatalytic reduction of hexavalent chromium with reduced pH dependence via alternating potential polarization using a polyaniline–chitosan composite electrode

Rongliang Qiu, Yetao Tang, Ye Xiao, Huihui Zheng, Wei Xian
article en
1 citations

Abstract

The slow kinetics and strong pH dependence of hexavalent chromium, Cr(VI), electroreduction pose significant challenges for efficient remediation. Herein, an innovative alternating potential technique coupled with a polyaniline/chitosan composite electrode is developed to achieve rapid Cr(VI) removal (up to 17.8 h<sup>-1</sup> at pH ∼ 2.0) while mitigating pH sensitivity (1.2 h<sup>-1</sup> at pH ∼ 5.0).

Chemical CommunicationsVol. 61(59)
South China Agricultural University (CN), Sun Yat-sen University (CN), Key Laboratory of Guangdong Province (CN)
National Natural Science Foundation of China, Natural Science Foundation of Guangdong Province, Guangzhou Municipal Science and Technology Project, National Key Research and Development Program of China
Openalex Percentile: Top 41%
Electrochemical Analysis and Applications
0.52
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