Proof of the Nernst theorem

Abstract The Nernst heat theorem is proven from purely thermodynamic arguments connected with the second law of thermodynamics. The proof stipulates that $$T=0$$ <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"> <mml:mrow> <mml:mi>T</mml:mi> <mml:mo>=</mml:mo> <mml:mn>0</mml:mn> </mml:mrow> </mml:math> is formalized by a Carnot thermometer, and is independent of the vanishing of the specific heats, or the unattainability of the zeroth isotherm. With this proof, the second law of thermodynamics would extend its applicability, and the third postulate of thermodynamics would be narrowed to the fact that the entropy of a finite density, chemically homogeneous body must not be negative.

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Publication Details

Journal
The European Physical Journal Plus
Published
2025-06-13
DOI
https://doi.org/10.1140/epjp/s13360-025-06503-w
Citations
2
Primary Topic
History and Theory of Mathematics
Type
article
Field-Weighted Citation Impact
57.16

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article

Proof of the Nernst theorem

José María Martín‐Olalla
2 citations
The European Physical Journal Plus
History and Theory of Mathematics
57.16
article

Proof of the Nernst theorem

José María Martín‐Olalla
article en
2 citations

Abstract

Abstract The Nernst heat theorem is proven from purely thermodynamic arguments connected with the second law of thermodynamics. The proof stipulates that $$T=0$$ <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"> <mml:mrow> <mml:mi>T</mml:mi> <mml:mo>=</mml:mo> <mml:mn>0</mml:mn> </mml:mrow> </mml:math> is formalized by a Carnot thermometer, and is independent of the vanishing of the specific heats, or the unattainability of the zeroth isotherm. With this proof, the second law of thermodynamics would extend its applicability, and the third postulate of thermodynamics would be narrowed to the fact that the entropy of a finite density, chemically homogeneous body must not be negative.

The European Physical Journal PlusVol. 140(6)
Universidad de Sevilla (ES)
Universidad de Sevilla
Openalex Percentile: Top 0%
History and Theory of Mathematics
57.16
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