Electron-rich phenanthroline bearing N-heterocyclic imine substituents: synthesis, optical properties, metal coordination
A new electron-rich 1,10-phenanthroline ligand with bulky NHI groups forms a well-structured coordination cavity, showing selective coordination of Lewis acids at phenanthroline nitrogen atoms and tunable electronic and photophysical properties.
Authors
- Thomas S. Hofer (ORCID: https://orcid.org/0000-0002-6559-1513)
- Mark E. Thompson (ORCID: https://orcid.org/0000-0002-7764-4096)
- Michael Seidl (ORCID: https://orcid.org/0000-0002-5218-2083)
- Xue‐Quan Zhou (ORCID: https://orcid.org/0000-0003-0676-5808)
- Luisa De Cola (ORCID: https://orcid.org/0000-0002-2152-6517)
- Fabian Dielmann (ORCID: https://orcid.org/0000-0002-7025-5450)
- Lukas F. B. Wilm
- Austin Mencke (ORCID: https://orcid.org/0000-0002-5931-9572)
- Peter Brüggeller (ORCID: https://orcid.org/0000-0001-9411-6554)
- J. Franzen
- Kelly Biv (ORCID: https://orcid.org/0009-0005-8587-8190)
- Alessandro Ajò
Institutions
- University of Southern California (US)
- University of Milan (IT)
- Universität Innsbruck (AT)
- Mario Negri Institute for Pharmacological Research (IT)
- University of Münster (DE)
Publication Details
- Journal
- Inorganic Chemistry Frontiers
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5qi00957j
- Citations
- 2
- Primary Topic
- Magnetism in coordination complexes
- Type
- article
- Field-Weighted Citation Impact
- 0.85