Effects of Water-to-Cement and Sand-to-Binder Ratio on Mechanical and Drying Shrinkage Properties of Low-Carbon Mortar Containing Biochar Aggregate

Biochar, serving as a carbon sequestration material, has garnered significant attention. In this study, the effects of water-to-cement (W/C) and sand-to-binder (S/B) ratio on the macroscopic mechanical properties, dry-shrinkage behavior, and water transport properties of biochar mortar, as well as the microstructure of the mortar, are described. The results indicate that the compressive strength of the mortar decreases gradually with increases in the S/B ratio, while its flexural strength increases gradually with increases in the S/B ratio. Meanwhile, with increases in W/C and S/B, the drying shrinkage rate decreases, and the extent of water loss tends to be comparable to the drying shrinkage rate. The water absorption of biochar mortar increases as the W/C and S/B ratios increase. This is also reflected in the depth of water ingress in biochar mortars, which increases significantly with rising W/C and S/B ratios. Moreover, the water absorption coefficients of different mortars vary significantly only in the first few hours, and their final water absorption coefficients and ingress depths are similar. The SEM results indicate that biochar can provide nucleation points for hydration products to form a unique binding mechanism between them and the cement matrix. In addition, when the sand-to-cement ratio reaches 1.15, biochar reduces CO₂ emissions by 104.57 kg, and biochar mortar shows good potential for CO₂ sequestration.