Synthesis of Quinolines via C‐H Activation/Cyclization of Anilines with Alkynes Using Heterogeneous CoO@rGO Catalyst

Abstract A heterogeneous cobalt‐catalyzed synthesis of 4‐aryl‐2‐methyl quinolines from cheap and easily available anilines via C‐H bond activation/cyclization in the presence of PEG‐400 and TfOH is reported here. The cobalt catalyst was easily prepared and characterized, and PEG‐400 served as a carbon source in addition to being a solvent. Easy separation and reusability of the catalyst and reaction medium (PEG‐400) make the protocol green and sustainable.

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Publication Details

Journal
ChemCatChem
Published
2025-06-11
DOI
https://doi.org/10.1002/cctc.202500816
Citations
1
Primary Topic
Catalytic C–H Functionalization Methods
Type
article
Field-Weighted Citation Impact
0.94

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article

Synthesis of Quinolines via C‐H Activation/Cyclization of Anilines with Alkynes Using Heterogeneous CoO@rGO Catalyst

Amarta Kumar Pal, Fillip Kumar Sarkar, Lenida Kyndiah, Priyanka Borah et al.
1 citations
ChemCatChem
Catalytic C–H Functionalization Methods
0.94
article

Synthesis of Quinolines via C‐H Activation/Cyclization of Anilines with Alkynes Using Heterogeneous CoO@rGO Catalyst

Amarta Kumar Pal, Fillip Kumar Sarkar, Lenida Kyndiah, Priyanka Borah, Rona Moni Bora
article en
1 citations

Abstract

Abstract A heterogeneous cobalt‐catalyzed synthesis of 4‐aryl‐2‐methyl quinolines from cheap and easily available anilines via C‐H bond activation/cyclization in the presence of PEG‐400 and TfOH is reported here. The cobalt catalyst was easily prepared and characterized, and PEG‐400 served as a carbon source in addition to being a solvent. Easy separation and reusability of the catalyst and reaction medium (PEG‐400) make the protocol green and sustainable.

ChemCatChemVol. 17(16)
North Eastern Hill University (IN)
North-Eastern Hill University, Department of Biotechnology, Ministry of Science and Technology, India, Indian Institute of Technology Guwahati, Science and Engineering Research Board, North East Centre for Biological Sciences and Healthcare Engineering, Indian Institute of Technology Guwahati
Openalex Percentile: Top 25%
Catalytic C–H Functionalization Methods
0.94
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