Effective reaction kinetics of steady mixing fronts in porous media

Mixing-induced reactions play an important role in a wide range of porous media processes. Recent advances have shown that fluid flow through porous media leads to chaotic advection at the pore scale. However, how this impacts Darcy-scale reaction rates is unknown. Here, we measure the reaction rates in steady mixing fronts using a chemiluminescence reaction in index-matched three-dimensional porous media. We consider two common mixing scenarios for reacting species, flowing either in parallel in a uniform flow or towards each other in a converging flow. We study the reactive properties of these fronts for a range of Péclet numbers. In both scenarios, we find that the reaction rates significantly depart from the prediction of hydrodynamic dispersion models, which obey different scaling laws. We attribute this departure to incomplete mixing effects at the pore scale, and propose a mechanistic model describing the pore-scale deformations of the front triggered by chaotic advection and their impact on the reaction kinetics. The model shows good agreement with the effective Darcy-scale reaction kinetics observed in both uniform and converging flows, opening new perspectives for upscaling reactive transport in porous media.