Spin Coherence and Electron Spin Distribution of a Silver(II) <i>S</i> = 1/2 Molecular System
The spin-lattice relaxation time, spin coherence, and spin distribution have been studied through ac susceptometry, pulse EPR, and ultralow-frequency Raman spectroscopy on a silver(II)-derived molecular system with spin 1/2. The combination of magnetometry and spectroscopy techniques demonstrates the occurrence of slow spin magnetic relaxation induced by a spin-phonon interaction. The magnetic behavior and the spin coherence of this Ag<sup>II</sup>-derived system open the door to a new cation into the scarce family of <i>S</i> = 1/2 slow magnetic relaxing systems for further applications in quantum technologies.
Authors
- Júlia Mayans (ORCID: https://orcid.org/0000-0001-8875-8075)
- Albert Gallén (ORCID: https://orcid.org/0000-0002-9563-8802)
- Mario Chiesa (ORCID: https://orcid.org/0000-0001-8128-8031)
- Yu‐Kai Liao (ORCID: https://orcid.org/0000-0002-8090-2025)
- Joan Serra (ORCID: https://orcid.org/0000-0001-7646-0562)
- Albert Escuer (ORCID: https://orcid.org/0000-0002-6274-6866)
Institutions
- Institut de Nanociència i Nanotecnologia de la Universitat de Barcelona
- University of Turin (IT)
- Universitat de Barcelona (ES)
Publication Details
- Journal
- Inorganic Chemistry
- Published
- 2025-06-11
- DOI
- https://doi.org/10.1021/acs.inorgchem.5c00203
- Citations
- 1
- Primary Topic
- Magnetism in coordination complexes
- Type
- article
- Field-Weighted Citation Impact
- 0.43
Funders
- Ministerio de Ciencia, Tecnología e Innovación Productiva
- Ministero dell'Università e della Ricerca