Exploring the Thermal and Mechanical Properties of Thermoset-Based Composites Reinforced with New Continuous and Chopped Phosphate Glass Fibers

Currently, the main drivers for the production of phosphate glass fiber-reinforced composites are the growing demand for lightweight materials, reduced energy consumption, improved durability, and minimized environmental impact. This study aims to develop thermoset-based composites using chopped and continuous phosphate glass fibers (PGFs) combined with polyester and epoxy matrices, processed via contact molding. Physical, mechanical, thermal, and morphological characterizations were conducted. The addition of PGFs led to a steady increase in density and fiber volume fraction. For polyester composites with short PGFs, density rose from 1.60 g/cm³ (0 wt%) to 1.77 g/cm³ (22.8 wt%), with a corresponding volume fraction increase from 0% to 14.4%. Similarly, epoxy composites showed density values from 1.70 g/cm³ to 1.87 g/cm³ and volume fractions up to 15.2%. Thermogravimetric analysis (TGA) showed that as the fiber content increased, the thermal degradation of the resin was delayed, as evidenced by a rise in onset degradation temperature and greater residual mass-indicating improved thermal stability of the composites. Tensile strength increased from 20.8 MPa to 71.3 MPa (polyester) and from 26.8 MPa to 75.9 MPa (epoxy) with chopped fibers, reaching 145.7 MPa and 187.9 MPa, respectively, with continuous fibers. Flexural strength reached 167.9 MPa (polyester) and 218.0 MPa (epoxy) in continuous-fiber configurations. Young's modulus values closely matched Hirsch model predictions. These findings confirm the potential of PGF-reinforced thermoset composites for high-performance and sustainable material applications.