Selective hydroborative reduction of isocyanate using recyclable Ni-based metal–organic framework catalysts
Ni-MOF-74 decorated with amino groups exhibited efficient and selective catalysis for partial reduction of aryl and alkyl isocyanates into N -borylated formamides and N -methylamines, respectively, with conversion retention of over 90% after 7 cycles.
Authors
- Yang Huang (ORCID: https://orcid.org/0000-0001-5060-3414)
- Mengtao Ma (ORCID: https://orcid.org/0000-0001-9629-6464)
- Xinyi Li (ORCID: https://orcid.org/0000-0001-5590-4435)
- Ying Zhao (ORCID: https://orcid.org/0000-0002-9478-6635)
- Zichen Wang (ORCID: https://orcid.org/0000-0001-8940-6792)
- Hainan Wang
- Guanxin Su
Institutions
- Nanjing Forestry University (CN)
- Yancheng Institute of Technology (CN)
Publication Details
- Journal
- New Journal of Chemistry
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5nj01744k
- Primary Topic
- Chemical Synthesis and Reactions
- Type
- article
- Field-Weighted Citation Impact
- 0.00