Intermolecular π-stacking stabilization of a new high-M/L-ratio coordination motif for a dinuclear Fe(<scp>iii</scp>) complex supported by a “salen-type” Schiff base derivative of <i>o</i>-xylylenediamine
Control over the self-assembly of cluster complexes is of high importance. In this respect, intermolecular noncovalent interactions play a crucial role. An unprecedented dinuclear Fe(III) complex, supported by an <i>o</i>-xylylenediamine Schiff base derivative and stabilized by intermolecular π-stacking is reported, paving a way for designing new functional 3d metal complexes.
Authors
- А. V. Pyataev (ORCID: https://orcid.org/0000-0001-6313-6130)
- Alexander S. Ovsyannikov (ORCID: https://orcid.org/0000-0002-5941-844X)
- S. Е. Solovieva (ORCID: https://orcid.org/0000-0001-7106-6777)
- Igor S. Antipin (ORCID: https://orcid.org/0000-0002-9882-7035)
- Ayrat R. Khamatgalimov (ORCID: https://orcid.org/0000-0002-2865-8619)
- L. V. Frantsuzova (ORCID: https://orcid.org/0000-0003-1119-0906)
- D. P. Gerasimova (ORCID: https://orcid.org/0000-0001-9770-196X)
- Ilya D. Shutilov
- Pavel A. Volodin
Institutions
- Kazan Federal University (RU)
- A.E. Arbuzov Institute of Organic and Physical Chemistry (RU)
Publication Details
- Journal
- Dalton Transactions
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5dt00856e
- Primary Topic
- Metal-Organic Frameworks: Synthesis and Applications
- Type
- article
- Field-Weighted Citation Impact
- 0.00
Funders
- Russian Science Foundation