Ultracold interactions between ions and polar molecules

We propose a platform for observing and controlling the interactions between atomic ions and a quantum gas of polar molecules in the ultracold regime. This approach is based on the combination of several recently developed methods in two so-far complementary research domains: ion-atom collisions and studies of ultracold polar molecules. In contrast to collisions between ions and ground-state atoms, which are dominated by losses due to three-body recombination (TBR) already at densities far below those typical for quantum degenerate ensembles, our proposal makes use of polar molecules, their rich level structure, and sensitivity to electric fields to design effective interaction potentials where ion-neutral TBR losses and molecule-molecule losses due to sticky collisions could be strongly suppressed. This may open a broad range of applications including precise control of collisional properties in molecular ensembles using ions, quantum simulations, and cold quantum chemistry between polyatomic molecules.

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Publication Details

Journal
Physical Review Research
Published
2025-06-06
DOI
https://doi.org/10.1103/7zz8-qk2c
Citations
1
Primary Topic
Cold Atom Physics and Bose-Einstein Condensates
Type
article
Field-Weighted Citation Impact
1.25
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article

Ultracold interactions between ions and polar molecules

Olivier Dulieu, Karl J. Friston
1 citations
Physical Review Research
Cold Atom Physics and Bose-Einstein Condensates
1.25
article

Ultracold interactions between ions and polar molecules

Olivier Dulieu, Karl J. Friston
article en
1 citations

Abstract

We propose a platform for observing and controlling the interactions between atomic ions and a quantum gas of polar molecules in the ultracold regime. This approach is based on the combination of several recently developed methods in two so-far complementary research domains: ion-atom collisions and studies of ultracold polar molecules. In contrast to collisions between ions and ground-state atoms, which are dominated by losses due to three-body recombination (TBR) already at densities far below those typical for quantum degenerate ensembles, our proposal makes use of polar molecules, their rich level structure, and sensitivity to electric fields to design effective interaction potentials where ion-neutral TBR losses and molecule-molecule losses due to sticky collisions could be strongly suppressed. This may open a broad range of applications including precise control of collisional properties in molecular ensembles using ions, quantum simulations, and cold quantum chemistry between polyatomic molecules.

Physical Review ResearchVol. 7(2)
Leibniz University Hannover (DE), Laboratoire Aimé Cotton (FR)
Openalex Percentile: Top 20%
Cold Atom Physics and Bose-Einstein Condensates
1.25
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Ultracold interactions between ions and polar molecules — Olivier Dulieu, Karl J. Friston · Physical Review Research (2025) | TGRS Research Map | TGRS