Energy Levels, Lifetimes, and Transition Properties for N iii – v

We present excitation energies, transition wavelengths, electric dipole (E1) transition rates, oscillator strengths, line strengths, and lifetimes for the 86 lowest states up to and including 1s22s27f in N iii, the 125 lowest states up to and including 1s22s7f in N iv, and the 53 lowest states up to 1s28g in N v using the multiconfiguration Dirac–Hartree–Fock (MCDHF) and relativistic configuration interaction (RCI) methods. The computed results are then compared with data from the Atomic Spectra Database of the National Institute of Standards and Technology (NIST-ASD), experimental results, and other theoretical studies. For all levels in N iii – v, the root mean square energy differences from the NIST values are 130, 103, and 6 cm−1, respectively. Compared to previous multiconfiguration Hartree–Fock and the Breit–Pauli (MCHF-BP) calculations, 89.3%, 98.5%, and 100% of the log(gf) values for N iii – v agree within 5%, respectively.

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Publication Details

Journal
Atoms
Published
2025-06-06
DOI
https://doi.org/10.3390/atoms13060049
Primary Topic
Cosmology and Gravitation Theories
Type
article
Field-Weighted Citation Impact
0.00

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article

Energy Levels, Lifetimes, and Transition Properties for N iii – v

Kaijian Huang, Juan Du, Meichun Li, Wenxian Li
Atoms
Cosmology and Gravitation Theories
article

Energy Levels, Lifetimes, and Transition Properties for N iii – v

Kaijian Huang, Juan Du, Meichun Li, Wenxian Li
article en

Abstract

We present excitation energies, transition wavelengths, electric dipole (E1) transition rates, oscillator strengths, line strengths, and lifetimes for the 86 lowest states up to and including 1s22s27f in N iii, the 125 lowest states up to and including 1s22s7f in N iv, and the 53 lowest states up to 1s28g in N v using the multiconfiguration Dirac–Hartree–Fock (MCDHF) and relativistic configuration interaction (RCI) methods. The computed results are then compared with data from the Atomic Spectra Database of the National Institute of Standards and Technology (NIST-ASD), experimental results, and other theoretical studies. For all levels in N iii – v, the root mean square energy differences from the NIST values are 130, 103, and 6 cm−1, respectively. Compared to previous multiconfiguration Hartree–Fock and the Breit–Pauli (MCHF-BP) calculations, 89.3%, 98.5%, and 100% of the log(gf) values for N iii – v agree within 5%, respectively.

AtomsVol. 13(6)
Chinese Academy of Sciences (CN), National Astronomical Observatories (CN), Huizhou University (CN)
National Natural Science Foundation of China, National Key Research and Development Program of China, Basic and Applied Basic Research Foundation of Guangdong Province
Openalex Percentile: Top 92%
Cosmology and Gravitation Theories
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Energy Levels, Lifetimes, and Transition Properties for N iii – v — Kaijian Huang, Juan Du, et al. · Atoms (2025) | TGRS Research Map | TGRS