Europium Coordination Compounds for the Design of a Polyethylene-Based Luminescent Composite Material

The reaction of europium dibenzoylmethanate complex Na+[Eu(Dbm)4]– with 1-alkyl-4-dimethylaminopyridinium salts gives compounds [RNC5H4NMe2]+[Eu(Dbm)4]– (Dbm = [PhC(O)CHC(O)–Ph]), where R = C10H21 (I) or a set of oligomers CnH2n+1, (n is even) ([(R-NC5H4NMe2)]I) with a weight-average molecular weight Mw = 1520 (II). The molecular structure of complex I was established by X-ray diffraction analysis (CCDC no. 2405293). Compounds I and II were used as the luminescent components for a luminescent composite material based on low-density polyethylene (LDPE). The optical properties of complexes I and II and LDPE-based composite materials prepared using I and II were investigated.

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Publication Details

Journal
Russian Journal of Coordination Chemistry
Published
2025-03-01
DOI
https://doi.org/10.1134/s1070328424601432
Primary Topic
Lanthanide and Transition Metal Complexes
Type
article
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article

Europium Coordination Compounds for the Design of a Polyethylene-Based Luminescent Composite Material

Evgenia A. Varaksina, Mikhail Evgenievich Minyaev, Dmitrii M. Roitershtein, I. E. Nifantiev et al.
Russian Journal of Coordination Chemistry
Lanthanide and Transition Metal Complexes
article

Europium Coordination Compounds for the Design of a Polyethylene-Based Luminescent Composite Material

Evgenia A. Varaksina, Mikhail Evgenievich Minyaev, Dmitrii M. Roitershtein, I. E. Nifantiev, Lada N. Puntus
article en

Abstract

The reaction of europium dibenzoylmethanate complex Na+[Eu(Dbm)4]– with 1-alkyl-4-dimethylaminopyridinium salts gives compounds [RNC5H4NMe2]+[Eu(Dbm)4]– (Dbm = [PhC(O)CHC(O)–Ph]), where R = C10H21 (I) or a set of oligomers CnH2n+1, (n is even) ([(R-NC5H4NMe2)]I) with a weight-average molecular weight Mw = 1520 (II). The molecular structure of complex I was established by X-ray diffraction analysis (CCDC no. 2405293). Compounds I and II were used as the luminescent components for a luminescent composite material based on low-density polyethylene (LDPE). The optical properties of complexes I and II and LDPE-based composite materials prepared using I and II were investigated.

Russian Journal of Coordination ChemistryVol. 51(3)
National Research University Higher School of Economics (RU), P.N. Lebedev Physical Institute of the Russian Academy of Sciences (RU), Russian Academy of Sciences (RU), Lomonosov Moscow State University (RU), N.D. Zelinsky Institute of Organic Chemistry (RU), A.V. Topchiev Institute of Petrochemical Synthesis (RU), Kotelnikov Institute of Radioengineering and Electronics of the Russian Academy of Sciences (RU)
Openalex Percentile: Top 91%
Lanthanide and Transition Metal Complexes
DOISourceOpenAlex
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Europium Coordination Compounds for the Design of a Polyethylene-Based Luminescent Composite Material — Evgenia A. Varaksina, Mikhail Evgenievich Minyaev, et al. · Russian Journal of Coordination Chemistry (2025) | TGRS Research Map | TGRS