Remote activating strategy enabled (RASE) π-bond migratory dealkylative C–N coupling utilising <i>N</i>-fluorobenzenesulfonimide (NFSI) as a bifunctional domino reagent

A remote activating strategy enabled (RASE) π-bond migratory dealkylative C(sp 3 )–N and C(sp 2 )–N coupling with 2-alkoxylthiazole to afford N -benzyl or N -phenyl thiazol-2(3 H )-ones is reported.

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Publication Details

Journal
Organic Chemistry Frontiers
Published
2025-01-01
DOI
https://doi.org/10.1039/d5qo00480b
Primary Topic
Catalytic C–H Functionalization Methods
Type
article
Field-Weighted Citation Impact
0.00

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article

Remote activating strategy enabled (RASE) π-bond migratory dealkylative C–N coupling utilising N-fluorobenzenesulfonimide (NFSI) as a bifunctional domino reagent

Xiangmin Tian, Jiahao Gu, Zhenyang Wan, Dailin Zhuang et al.
Organic Chemistry Frontiers
Catalytic C–H Functionalization Methods
article

Remote activating strategy enabled (RASE) π-bond migratory dealkylative C–N coupling utilising N-fluorobenzenesulfonimide (NFSI) as a bifunctional domino reagent

Xiangmin Tian, Jiahao Gu, Zhenyang Wan, Dailin Zhuang, Zhuo Zeng, Ziyuan Li, Yuhong Lu
article en

Abstract

A remote activating strategy enabled (RASE) π-bond migratory dealkylative C(sp 3 )–N and C(sp 2 )–N coupling with 2-alkoxylthiazole to afford N -benzyl or N -phenyl thiazol-2(3 H )-ones is reported.

Organic Chemistry Frontiers
Sichuan University (CN), Chengdu University of Technology (CN)
National Natural Science Foundation of China, Department of Science and Technology of Sichuan Province
Openalex Percentile: Top 91%
Catalytic C–H Functionalization Methods
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