Investigation of the Frequency-Dependent Dielectric Properties of the As-Prepared LaNiO<sub>3</sub>/Co<sub>3</sub>O<sub>4</sub> Nanocomposites

This article presents a detailed study of the dielectric properties, AC conductivity, electric modulus, and impedance spectroscopy of the LaNiO<sub>3</sub>/Co<sub>3</sub>O<sub>4</sub> as-prepared nanocomposite. The composite was prepared using the modified citrate gel autocombustion method. Transmission electron microscopy and atomic force microscopy images revealed nonuniform nanoparticles of varying shapes and sizes. Impedance analysis indicated a negative temperature coefficient of resistance and semiconducting behavior of the nanocomposite. The Nyquist plot displayed one semicircular curve. The AC conductivity was found to be dependent on both temperature and frequency, adhering to Jonscher's power law, with conductivity governed by a sudden hopping process. A high dissipation factor was observed, which decreased with frequency. A non-Debye relaxation type was defined for the nanocomposite.

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Publication Details

Journal
ACS Omega
Published
2025-06-02
DOI
https://doi.org/10.1021/acsomega.4c11199
Citations
9
Primary Topic
Ferroelectric and Piezoelectric Materials
Type
article
Field-Weighted Citation Impact
4.66

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article

Investigation of the Frequency-Dependent Dielectric Properties of the As-Prepared LaNiO3/Co3O4 Nanocomposites

Olfa Messaoudi, Arwa Azhary, A. Dhahri, Latifah Alfhaid, A. Mabrouki, Moufida Mansouri
article en
9 citations

Abstract

This article presents a detailed study of the dielectric properties, AC conductivity, electric modulus, and impedance spectroscopy of the LaNiO<sub>3</sub>/Co<sub>3</sub>O<sub>4</sub> as-prepared nanocomposite. The composite was prepared using the modified citrate gel autocombustion method. Transmission electron microscopy and atomic force microscopy images revealed nonuniform nanoparticles of varying shapes and sizes. Impedance analysis indicated a negative temperature coefficient of resistance and semiconducting behavior of the nanocomposite. The Nyquist plot displayed one semicircular curve. The AC conductivity was found to be dependent on both temperature and frequency, adhering to Jonscher's power law, with conductivity governed by a sudden hopping process. A high dissipation factor was observed, which decreased with frequency. A non-Debye relaxation type was defined for the nanocomposite.

ACS OmegaVol. 10(22)
University of Sfax (TN), Shaqra University (SA), Cal Humanities (US), University of Ha'il (SA)
University of Hail
Openalex Percentile: Top 5%
Ferroelectric and Piezoelectric Materials
4.66
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