Order–Disorder-Type Transitions Through a Multifractal Procedure in Cu-Zn-Al Alloys—Experimental and Theoretical Design
Experimental and theoretical design on thermal and structural properties of Cu-Zn-Al alloys are established. As such, from an experimental point of view, differential thermal analysis has been performed with the help of a DSC Netzsch STA 449 F1 Jupiter calorimeter with high levels of sensitivity, and the structural analysis has been accomplished through X-ray diffraction and SEM analysis. An unusual specific property for a metallic material has been discovered, which is known as "rubber-type behavior", a characteristic determined by micro-structural changes. From the theoretical point of view, the thermal transfer in Cu-Zn-Al is presented by assimilating this alloy, both structurally and functionally, with a multifractal, situation in which the order-disorder transitions assimilated with thermal "dynamics" of Cu-Zn-Al, are mimed through transitions from non-multifractal to multifractal curves. In such a context, the thermal expansion velocity contains both the propagation speed of the phase transformation (be it a direct one: austenitic-martensitic transformation, or an indirect one: martensitic-austenitic transformation) and the thermal diffusion speed. Then, through self-modulations of the thermal field, the Cu-Zn-Al alloy will self-structure in channel-type or cellular-type thermal patterns, which can be linked to obtained experimental data. Consequently, since the thermal conductivity becomes a function of the observation scale, and heat transfer is modified to reflect the multifractal, non-differentiable paths in the material, it leads to anomalous diffusion and complex thermal behaviors.
Authors
- Constantin Plăcintă
- Tudor-Cristian Petrescu (ORCID: https://orcid.org/0000-0003-0006-7048)
- Maricel Agop
- Valentin Nedeff
- Diana Mirilă (ORCID: https://orcid.org/0000-0002-0922-740X)
- Florin Nedeff (ORCID: https://orcid.org/0000-0003-3863-6904)
- Elena Puiu Costescu
- Mirela Panainte-Lehăduș (ORCID: https://orcid.org/0000-0002-8582-1988)
- Sergiu Stanciu (ORCID: https://orcid.org/0000-0002-3055-9871)
Institutions
- Alexandru Ioan Cuza University (RO)
- Academia Oamenilor de Știință din România (RO)
- Gheorghe Asachi Technical University of Iași (RO)
- University of Bacău (RO)
Publication Details
- Journal
- Entropy
- Published
- 2025-05-30
- DOI
- https://doi.org/10.3390/e27060587
- Primary Topic
- Shape Memory Alloy Transformations
- Type
- article
- Field-Weighted Citation Impact
- 0.00