Structure and reactivity of a triflimide-bridged bis(trimethylsilyl) cation
Preparation of a triflimide-bridged bis-silylium monocation [(Me<sub>3</sub>Si)<sub>2</sub>NTf<sub>2</sub>]<sup>+</sup> has been accomplished as a [HCB<sub>11</sub>Cl<sub>11</sub>]<sup>-</sup> salt. Its structure has been analyzed and its potency in halide abstraction illustrated.
Authors
- Oleg V. Ozerov (ORCID: https://orcid.org/0000-0002-5627-1120)
- Nattamai Bhuvanesh (ORCID: https://orcid.org/0000-0001-8712-9103)
- Joshua H. Daum
Institutions
- Texas A&M University (US)
Publication Details
- Journal
- Chemical Communications
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5cc01223f
- Primary Topic
- Organoboron and organosilicon chemistry
- Type
- article
- Field-Weighted Citation Impact
- 0.00
Funders
- U.S. Department of Energy
- Office of Science
- Basic Energy Sciences