Dual Activation of Molecular NO and O₂ on a Pr-Doped CeO₂-TiO₂ Catalyst for the Simultaneous Catalytic Purification of NO_<i>x</i> and Toluene

Designing a bifunctional catalyst to concurrently activate NO and O₂ is of fundamental importance to the simultaneous catalytic removal of NO_<i>x</i> and VOCs. During this process, sufficient electron transfer from the catalyst surface to the antibonding π* orbitals of adsorbed NO and O₂ is necessary to facilitate the adsorption and subsequent bond cleavage. Herein, an electronic orbital coupling strategy is applied by doping praseodymium (Pr) into a CeO₂-TiO₂ (CeTi) composite oxide to obtain a PrCeTi bifunctional catalyst, which has a strong interaction with NO to form NO⁺, further splitting with N³⁺ production and thereby enhancing NH₃-SCR performance following the Langmuir-Hinshelwood mechanism. Meanwhile, O₂ adsorbs on the PrCeTi catalyst surface to produce superoxide (O₂^-) and further transforms into peroxide (O₂^2-) which, along with increased temperature, boosts the PhCH₃ total oxidation. Finally, the coactivation of NO and O₂ over the PrCeTi catalyst contributes to its better simultaneous removal efficiency of NO_<i>x</i> and toluene than that of the CeTi catalyst.