Correlation between domain size and charge transport properties in benzothiadiazole–thiophene molecules: insights from nano-focus X-ray scattering and fast scanning chip calorimetry

Conjugated compounds including thiophene and benzothiadiazole units are promising candidates for next-generation semiconductor materials. Precise control over morphology and crystal orientation is critical for optimizing device performance. By employing a combination of synchrotron nano-focus X-ray scattering and fast chip calorimetry, a correlation was established between the size of ordered domains formed during isothermal crystallization and charge carrier mobility. These findings highlight the potential of advanced <i>in situ</i> techniques for fine-tuning the electronic properties of organic semiconductors.

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Publication Details

Journal
Physical Chemistry Chemical Physics
Published
2025-01-01
DOI
https://doi.org/10.1039/d5cp00876j
Primary Topic
Organic Electronics and Photovoltaics
Type
article
Field-Weighted Citation Impact
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article

Correlation between domain size and charge transport properties in benzothiadiazole–thiophene molecules: insights from nano-focus X-ray scattering and fast scanning chip calorimetry

M V Gaikovich, A. A. Piryazev, Azaliia F. Akhkiamova, Alexander V. Akkuratov et al.
Physical Chemistry Chemical Physics
Organic Electronics and Photovoltaics
article

Correlation between domain size and charge transport properties in benzothiadiazole–thiophene molecules: insights from nano-focus X-ray scattering and fast scanning chip calorimetry

M V Gaikovich, A. A. Piryazev, Azaliia F. Akhkiamova, Alexander V. Akkuratov, Ainur F. Abukaev, Denis V. Anokhin, Dimitri A. Ivanov, Ilya I. Rulev, Ilya E. Kuznetsov
article en

Abstract

Conjugated compounds including thiophene and benzothiadiazole units are promising candidates for next-generation semiconductor materials. Precise control over morphology and crystal orientation is critical for optimizing device performance. By employing a combination of synchrotron nano-focus X-ray scattering and fast chip calorimetry, a correlation was established between the size of ordered domains formed during isothermal crystallization and charge carrier mobility. These findings highlight the potential of advanced <i>in situ</i> techniques for fine-tuning the electronic properties of organic semiconductors.

Physical Chemistry Chemical PhysicsVol. 27(24)
Centre National de la Recherche Scientifique (FR), Lomonosov Moscow State University (RU), Université de Haute-Alsace (FR), Sirius University of Science and Technology (RU), Institut de Sciences des Matériaux de Mulhouse (FR), Institute of Problems of Chemical Physics (RU)
Openalex Percentile: Top 90%
Organic Electronics and Photovoltaics
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