Alkylaluminium-catalyzed regioselective hydrophosphinylation of α,β-unsaturated ketones into γ-ketophosphine oxides
A green method for regioselective hydrophosphinylation of α,β-unsaturated ketones using alkylaluminium compounds has been developed. It proceeds without acids, bases, or additives, yielding γ-ketophosphine oxides efficiently. This process offers excellent atom economy, functional group tolerance, and high yields in a short time.
Authors
- Ziyuan Pang
- Xiaobo Yang (ORCID: https://orcid.org/0000-0003-0684-8419)
- Zhi Mao Yang (ORCID: https://orcid.org/0000-0002-5732-0326)
- Gege Li (ORCID: https://orcid.org/0009-0006-6706-0931)
- Xiaoli Ma (ORCID: https://orcid.org/0000-0003-2632-5367)
- Yiwen Chen (ORCID: https://orcid.org/0000-0002-7706-7540)
- Qifeng Li (ORCID: https://orcid.org/0000-0003-2258-8987)
- Dong Xuan (ORCID: https://orcid.org/0000-0002-3121-9756)
- Wenliang Yan
Institutions
- Beijing Institute of Technology (CN)
Publication Details
- Journal
- Chemical Communications
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5cc01440a
- Primary Topic
- Organophosphorus compounds synthesis
- Type
- article
- Field-Weighted Citation Impact
- 0.00